Discuss the conditions for spontaneity of a process .

The condition for spontaneity of process is

The condition for spontaneity of a process is-

What are spontaneous reactions? What are the conditions for the spontaneity of a process?

DeltaG of the system alone provides a criterion for the spontaneity of a process at constant temperature & pressure, DeltaG system lt 0 (spontaneous) DeltaG system = 0 (equilibrium) DeltaG system gt 0 {(non-spontaneous) Again DeltaG^@ is related to the equilibrium constant as follows : DeltaG^@ = 2.303 RT log K_e If both DeltaH and Delta S are negative, the reaction will be spontaneous

For spontaneous process—

Write down the conditions of reversibility of a process.

(i) Spontaneity of a process can be determined from the entropy change and also from the Gibbs free energy change. But the Gibbs free energy change in more useful than entropy change to determine the spontaneity of a process. Explain it. (ii) Show that Gibbs energy change of a system at certain temperature and pressure, DeltaG=DeltaH-TDeltaS .

Which of the following conditions favours the spontaneity of a reaction at a constant temperature and pressure? DeltaH gt0, DeltaH lt 0, DeltaS gt0, DeltaS lt 0 .

Give the mathematical definition of entropy change. Discuss the relationship between entropy change & spontaneity of a process.