Home
Class 12
CHEMISTRY
aArarr bB is a first order reaction with...

`aArarr bB` is a first order reaction with respect to A. The rate of this reaction can be determined from any of the following equations : `-(d[A])/(dt)=k_(1)[A] and (d[B])/(dt)=k_(2)[A] `. Deduce the relation between `k_(1) and k_(2)`.

Text Solution

Verified by Experts

`-(1)/(a)(d[A])/(dt)=(1)/(b)(d[B])/(dt)`
Here, `-(d[A])/(dt)=k_(1)[A] and (d[B])/(dt)=k_(2)[A]`
`therefore(k_(1))/(a)[A] =(k_(1))/(b)[A] " or, "k_(1)xxb=k_(2)xxa`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise QUESTION-ANSWER ZONE FOR BOARD EXAMINATION (VERY SHORT ANSWER TYPE)|35 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER (2014)|3 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (NUMERICAL PROBLEMS)|37 Videos
  • BIOMOLECULES

    CHHAYA PUBLICATION|Exercise Practic Set 29|1 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos

Similar Questions

Explore conceptually related problems

For the first order reaction Ararr2B , rate can be expressed any one of the following rate equations. (1)-(d[A])/(dt)=k_(1) [A] (2) (d[B])/(dt)=k_(2) [A] Find the relation between k_(1) and k_(2) .

The reaction -rate of the reaction AB_(3)rarr(1)/(2)A_(2)+(3)/(2)B2 can be expressed by any one of the following equations : (-d[AB_(3)])/(dt)=k_(1)[AB_(3)], (d[A_(2)])/(dt)=k_(2)[AB_(3)] " or, " (d[B_(2)])/(dt)=k_(3)[AB_(3)] The ratio between k_(1) , k_(2)and k_(3) is -

The relation between k_1,k_2 and k_3 may be given as:

Identify the reaction order from the following rate constants. k=3 xx 10^-4s^-1

Deduce the relation between K_P and K_C for the following gaseous reaction : aA + bB ,' IL + mM

In the reaction 3A to 2B , rate of reaction +('d(B)')/(dt) is equal to

For the reaction , ArarrB products , rate k[A][B] . How can this reaction be transformed into a pseudo first order reaction ?

2A+3Drarr Product. If the order of the reaction with respect to A is 1 and with respect to D is 2, then the rate law of the reaction is............

Write down the Arrhenius equation relating the rate constant of reaction with temperature , mentioning what the terms indicate. If k_(1) and k_(2) be the rate constant of a reaction at temperature t_(1)^(@)C and t_(2)^(@)C , respectively, find out the relation between k_(1) ,k_(2) and t_(1) and t_(2) . Given that the activation energy (E_(a)) of the reaction remains unchanged within the temperature range mentioned. The rate constant of a reaction at 400K and 500K are 0.02s^(-1) and 0.08s^(-1) respectively . Determine the activation energy (E_(a)) of the reaction.

For the reaction N_(2) + 3 H_(2) hArr 2 NH_(3) equilibrium constant is K_(1) and that of for the reaction NH_(3) hArr (1)/(2) N_(2) + (3)/(2) H_(2) is K_(2) . (ii) Then calculate the relation between K_(1) and K_(2) .

CHHAYA PUBLICATION-CHEMICAL KINETICS-WARM UP EXERCISE
  1. Determine the order of the reaction involving decomposition of ammonia...

    Text Solution

    |

  2. Zinc reacts with HCl to form ZnCl(2) and H(2) why is it found that t...

    Text Solution

    |

  3. aArarr bB is a first order reaction with respect to A. The rate of thi...

    Text Solution

    |

  4. Mention any two factors affecting the rate constant of a reaction.

    Text Solution

    |

  5. The time taken for the combustion of one piece of coal in air is much ...

    Text Solution

    |

  6. For the reaction A+Brarr Product, the order of reaction with respect ...

    Text Solution

    |

  7. For the reaction PrarrR , the rate of the reaction = r. On doubling t...

    Text Solution

    |

  8. Consider the reaction ArarrB , which is carried out at a given tempera...

    Text Solution

    |

  9. For the reaction A+BrarrC , the initial rate was x"mol.L"^(-1).s^(-1) ...

    Text Solution

    |

  10. The units of rate constant and reaction -rate of a chemical reaction a...

    Text Solution

    |

  11. Many reaction do not have a definite overall order explain.

    Text Solution

    |

  12. Give an example of a reaction for each of the following type. (i) Z...

    Text Solution

    |

  13. (a) What do you mean by rate law of a reaction ? Highlight two importa...

    Text Solution

    |

  14. What are the terms that are associated with the rate equation ?

    Text Solution

    |

  15. Which one of them can be determined from the balanced chemical equatio...

    Text Solution

    |

  16. The unit of rate constant of a reaction is ("mol")^(-x).(dm)^(3x).s^(-...

    Text Solution

    |

  17. At a specific temperature , why does the rate of a reaction increase w...

    Text Solution

    |

  18. For the reaction : 2NO(2)(g)+F(2)(g)rarr2NO(2)F(g) the rate law is , r...

    Text Solution

    |

  19. Mention the significance of rate constant of a reaction.

    Text Solution

    |

  20. For the reaction : aA+bBrarrcC , the rate law is , r=k[A]^(m)[B]^(n) ...

    Text Solution

    |