Home
Class 12
CHEMISTRY
Give the rate equation , overall order a...

Give the rate equation , overall order and molecularity of the following elementary reactions.
(1) `A+BrarrC` (2) `2ArarrD`

Text Solution

Verified by Experts

In the rate equation of an elementary reaction , the power of the concentration terms of reactants is equal to the stoichiometric coefficient or number of moles of the reactants in the balanced equation of the reaction.
The overall order of an elementary reaction = molecularity of the reaction = total number of moles of reactants in the balanced equation of the reaction
(1) reaction rate = k [A] [B] and overall order = melecularity = (1+1) = 2
(2) reaction -rate = `k[A]^(2)` and overall order = melecularity = 2
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER (2014)|3 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER (2015)|9 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise WARM UP EXERCISE|55 Videos
  • BIOMOLECULES

    CHHAYA PUBLICATION|Exercise Practic Set 29|1 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos

Similar Questions

Explore conceptually related problems

The order and molecularity of an elementary reaction are the same - explain.

Write the rate equations and molecularity for the following elementary reactions: (a) NO_(2)(g)+NO_(2)(g)rarrNO_(3)(g)+NO(g) (b) Cl(g)+O_(3)(g)rarrClO(g)+O_(2)(g) (c) O_(3)(g)rarrO_(2)(g)+O(g) (d) 2NO(g)rarrN_(2)O_(2)(g) (e) (CH_(3))_(3)CBrrarr(CH_(3))_(3)C^(+)+Br^(-)

Establish the rate equation for 1st order reaction.

Extablish the rate equation of a zero order reaction with single reactant.

On the basis of rate equation show that a fist order reaction does never go to completion. For an elementary reaction A + B rarr C , the rate constant increases 10 times on increasing the temperature from 27^@C by 10 degrees, Find out the activation energy of the reaction.

From the rate equation of first order reaction, show first order reaction cannot reach completion.

Establish the integrated rate equation for a first order reaction involving a single reactant.

Obtain the inverse of the following matrix using elementary operations. A= ((0,1,2),(1,2,3),(3,1,1))

Establish the integrated rate equation for a first order reaction.

CHHAYA PUBLICATION-CHEMICAL KINETICS-QUESTION-ANSWER ZONE FOR BOARD EXAMINATION (VERY SHORT ANSWER TYPE)
  1. Why does not a fuel burn on its own air at normal condition of tempera...

    Text Solution

    |

  2. For which kind of reaction is the rate law predicted by the law of mas...

    Text Solution

    |

  3. For a reaction A+BrarrC , the rate doubles if the concentration of A i...

    Text Solution

    |

  4. For the reaction A+BrarrC , the experimentally obtained rate law is ,r...

    Text Solution

    |

  5. At a given temperature , the rate constant for the reaction ArarrB " i...

    Text Solution

    |

  6. According to the Arrhenius equation , what would the value of rate con...

    Text Solution

    |

  7. What would the effect of temperature be on the rate constant of a reac...

    Text Solution

    |

  8. For the reaction , ArarrB products , rate k[A][B] . How can this react...

    Text Solution

    |

  9. The reaction , A+2Brarr3C+4D , is first order with respect to both A a...

    Text Solution

    |

  10. Will the molecularity of a zero order reaction be zero ?

    Text Solution

    |

  11. For the reaction ArarrB , the initial reaction -rate gets halved when ...

    Text Solution

    |

  12. Which of the following reactions have the least probability of occuran...

    Text Solution

    |

  13. How do the following factors affect the rate constant of a reaction? (...

    Text Solution

    |

  14. Mention a similarity and a difference between the rate of reaction and...

    Text Solution

    |

  15. Explain why the reaction -rate does not proceed at a uniform rate duri...

    Text Solution

    |

  16. Give the rate equation , overall order and molecularity of the followi...

    Text Solution

    |

  17. How does the initial concentration of the reactant in a first order re...

    Text Solution

    |

  18. Show that the time of a first order reaction takes for 'the nth' fract...

    Text Solution

    |

  19. If the half-life of a first order reaction is T s , then show that aft...

    Text Solution

    |

  20. In presence of excess water, hydrolysis of methyl acetate in basic or ...

    Text Solution

    |