Home
Class 12
CHEMISTRY
In a first order reaction , the amount o...

In a first order reaction , the amount of reactant decomposed in the first 1 min is 1 % of its initial amount. What percent of the reactant will remain undecomposed after 1 hour from the start of the reaction ?

Text Solution

Verified by Experts

`k = (2.303)/(t)log.(a)/(a-x)=(2.303)/(1) log.(a)/(a-0.01a)=0.01"min"^(-1)`
`t=(2.303)/(k) log .(a)/(a-x) " or, "60=(2.303)/(0.01) log. (a)/(a-x)`
or, a - x = 0.549 `xxa`
`therefore ` Percentage of undissociated substance
`=(0.549xxa)/(a)xx100=54.9%`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (SHORT ANSWER-TYPE QUESTIONS)|36 Videos
  • BIOMOLECULES

    CHHAYA PUBLICATION|Exercise Practic Set 29|1 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos

Similar Questions

Explore conceptually related problems

The half life period of a first order reaction is 10 mins, what percentage of the reactant will remain after one hour?

In a first-order reaction, it takes the reactant 40.5 minutes to be 25% decomposed. Find the rate constant of the reaction.

A first order reaction takes 40 min for 30% decomposition . Calculate t_(1//2) .

t_(1//2) of a first order reaction is 15 min . Calculate the time for 80% completion of the reaction . If the initial concentration of the reactant is doubled , calculate the time taken for 80% completion of the reaction Give reasons.

Half life of a first order reaction is 10 mins what is the % of reaction completed in 100 mins?

The half -life of a first order reaction ArarrB is 10 min . What fraction of the reactant will be left behind after 1 h ?

Show that half life period of a first order reaction is independent of the initial concentration of the reactant.

A First order reaction takes 40 min for 30% decomposition. Calculate its rate constant

If the half-life of a first order reaction is T s , then show that after nTs [1-(1/2)^(n)] parts of the initial concentration of the reactant will take part in the reaction.

For a reaction , the graph obtained by plotting t_(1//2) of the reaction against initial concentrations [A]_(0) of the reactant is a straight line passing through the origin . The order of the reaction is -

CHHAYA PUBLICATION-CHEMICAL KINETICS-EXERCISE (NUMERICAL PROBLEMS)
  1. A first order reaction takes one hour for 50% completion How long will...

    Text Solution

    |

  2. The half -life of a first order reaction ArarrB is 10 min . What frac...

    Text Solution

    |

  3. In a first order reaction , the amount of reactant decomposed in the f...

    Text Solution

    |

  4. The half -life of a first order reaction is 40min . Calculate the time...

    Text Solution

    |

  5. The following data are obtained for the decomposition of H(2)O(2) " ...

    Text Solution

    |

  6. If decomposition of H(2)O(2) is a first order reaction , how long woul...

    Text Solution

    |

  7. Show that for a first order reaction , the time taken to reach 75% of ...

    Text Solution

    |

  8. ArarrB+C , the following records are obtained : {:(t(s),0,900,1800...

    Text Solution

    |

  9. To calculate the rate of decomposition of H(2)O(2) in an aqueous sol...

    Text Solution

    |

  10. The decomposition of ammonium nitrite was studied by placing the appar...

    Text Solution

    |

  11. The following data were obtained during the first order thermal decomp...

    Text Solution

    |

  12. The following data are obtained of the decomposition of N(2)O(4) " in...

    Text Solution

    |

  13. The decomposition of gaseous Cl(2)O(7) to gaseous Cl(2) and O(2) at ...

    Text Solution

    |

  14. The decomposition of gaseous Cl(2)O(7) to gaseous Cl(2) and O(2) at ...

    Text Solution

    |

  15. Calculate the Activation Energy (E(a)) of a reaction that follows the ...

    Text Solution

    |

  16. The decomposition of H(2)O(2) is a first order reaction . The rate co...

    Text Solution

    |

  17. The rate constant of decomposition of B is 4.8xx10^(3)s^(-1) " at "15...

    Text Solution

    |

  18. The time taken by a first order reaction to reach 10% completion at 29...

    Text Solution

    |

  19. Calculate the activation energy of the reaction whose rate constant fo...

    Text Solution

    |

  20. The rate constants of a reaction at 35^(@)C and 65^(@)C " are " 6.65x...

    Text Solution

    |