Home
Class 12
CHEMISTRY
In the solid state, PCl(5) is -...

In the solid state, `PCl_(5)` is -

A

covalent solid

B

octahedral

C

an ionic solid which contains octahedral `[PCl_(6)]^(+)` ion and tetrahedral `[PCl_(4)]^(-)` ions

D

an ionic solid which contains tetrahedral `[PCl_(4)]^(+)` ion and octahedral `[PCl_(6)]^(-)` ions

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise MULTIPLE CHOICE QUESTION|10 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise SHORT ANSWER TYPE|21 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise NEET|52 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise WARM UP EXERICSE|132 Videos
  • POLYMERS

    CHHAYA PUBLICATION|Exercise SOVLED CBSE SCANNER|18 Videos

Similar Questions

Explore conceptually related problems

In the soild state , PCl_(5) exists in the lonic form as [PCl_(4)]^(+) [PCl_(6)]^(-) . What are the shapes of these two ions ? Why ?

The shape of PCl_5 is

A solid substance 'A' is very hard and electrical insulator both in the solid state as well as in molten state. It has also very high melting point. Is the solid metal like silver or network solid like silicon carbide (SiC) ?

Identify the type of cyrstalline solid based on the following properties : (a) Conducts electricity in the molten state but in the solid state. (b) Very hard with melting point and acts as electrical insulator. (c) Conducts electricity in the solid state, malleable and ductile.

In the solid state which of the following is the structure of alanine?

PCl_5 is an important halide. In crystalline state it exists in ionic form. On reaction with water it forms different compounds Answer the following questions based on above passage: In crystalline state PCl_5 exists as

Quantum mechanical calcuations show that mathematical mixing of certain combinaaation of orbitals in a given atom forms hybrid orbitals. The spatial orientations of these new orbitals lead to more stable bonds and are consistent with the observed molecular shapes . The process of orbital mixing is called hybridization and the new atomic orbitals are called hybrid orbitals.- Conditions (i) The no. of hybrid orbitals equal the number of atomic orbitalsmixed. (ii)The type of hybrid orbitals obtained varies with the type of atomic orbitals mixed. Rules to determine hybrid orbitals. Method i:Count no .of atoms directiy attached to central atom + lone pairs+single electrons. Method II: Count sigma - bonds+co-ordinate bonds+ lone pair+single electrons. If the number comes one to be 2 implies sp 5 implies sp^3d/dsp^3 3 implies sp^2 6 implies sp^3d^2/d^2sp^3 4 implies sp^3/dsp^2 7 implies sp^3d^3 Answer the following questions based on above passage : Phosphorous pentachloride in gaseous state exists as a momomer. In solid state, it exists as PCl_5^+. PCl_6^- ions. The hybrid state of P atom in PCl_5 is sp^3d . The hybrid state of P atoms in PCl_4^+ and PCl_6^- will be respectively

What is the hybrid state of BeCl_2 in solid and vapour state?

CHHAYA PUBLICATION-P-BLOCK ELEMENTS-SOLVED NCERT EXMPLAR PROBLEMS
  1. A gas is evolved when white phosphours is heated with concentrated N...

    Text Solution

    |

  2. Which one of the following acids form 3 types of salts -

    Text Solution

    |

  3. The strong reducing property of H(3)PO(2) is due to -

    Text Solution

    |

  4. When lead nitrate is heated , oxides fo nitrogen and lead are ob...

    Text Solution

    |

  5. Which one of the following elements does not exhibits allotrophy ...

    Text Solution

    |

  6. The highest covlency of nitrogen is -

    Text Solution

    |

  7. Which of the following statements is not correct -

    Text Solution

    |

  8. The substance responsible for the appearance of a brown ring in the r...

    Text Solution

    |

  9. The elements of group-15 form compounds In +5 oxidation state. However...

    Text Solution

    |

  10. The substances obtained on heating ammonium dichromate and barium azid...

    Text Solution

    |

  11. In the manufacture of HNO(3) NO is prepared by the catalytic oxidat...

    Text Solution

    |

  12. The oxidation number of the central atom of the anion of the compound...

    Text Solution

    |

  13. Which one of the following is not tetrahedral In shape -

    Text Solution

    |

  14. Which one of the following is a peroxoacld of sulphur -

    Text Solution

    |

  15. Hot and concentrated H(2)SO(4) is a strong oxidising agent. It oxidise...

    Text Solution

    |

  16. A black compound of Mn reacts with a halogen acid to form a greenish ...

    Text Solution

    |

  17. Preparation of xenon compounds by Neil Bartlett ls based on the compou...

    Text Solution

    |

  18. In the solid state, PCl(5) is -

    Text Solution

    |

  19. Reduction potential values of some Ions are given below. Arrange them ...

    Text Solution

    |

  20. Which one of the following pair ls isoelectronic -

    Text Solution

    |