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Identify the isomeric alkanes (molecular...

Identify the isomeric alkanes (molecular formula = `C_(5)H_(12)`)which produce
(i) a single monochloride.

Text Solution

Verified by Experts

The alkane which produces only one monochloride must have equivalent H-atom. Therefore, the alkane is neopentane or 2,2-dimethylpropane `[(CH_3)_(4)C]`.
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Which one of the isomeric alkanes (molecular formulaL C_(5)H_(12) ) undergo free radial chlorination to yield - (iii) four isomeric monochloro derivatives?

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