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Explain the observation: (CH3)(3)C CH(...

Explain the observation:
`(CH_3)_(3)C CH_(2)Clunderset(300^(@)C)overset(AlCl_(3))(rarr)(CH_3)_(2)C ClCH_(2)CH_(3)`

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Consider the reactions: (i) (CH_3)_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)(rarr)(CH_3)_(2)CH-CH_(2)OC_(2)H_(5)+HBr (ii) (CH_3)_(2)CH-CH_(2)Broverset(C_(2)H_(5)O^(-))(rarr)(CH_3)_(2)CH-CH_(2)OC_(2)H_(5)+Br^(-) . Mechanism of reactions (i) and (ii) are respectively-

Complete the reaction : CH_(3)-underset(CH_(3))underset(|)(CH)-O-CH_(2)-CH_(3)overset(HI)rarr

2 -chloro 2 - methylpentane on reaction with sodium methoxide in methanol yields : C_(2)H_(5)CH_(2)underset((a))underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OCH_(3) " " C_(2)H_(5)CH_(2)underset((b))underset(CH_(3))underset(|)C =CH_(2) " " C_(2)H_(5)CH=underset ((c))underset (CH_(3))underset(|)C-CH_(3)

Arrange the following compounds in the order of increasing S_(N)2 reactivity and explain the order: CH_(3)CH_(2)CH_(2)Br, CH_(3)CH_(3)Br, (CH_3)_(3)C CH_(2)Br, (CH_3)_(2)CHCH_(2)Br.

Major product of the given reaction is CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-underset(CI)underset(|)(CH)-CH_(3)overset(C_(2)H_(5)O^-)rarr

CHHAYA PUBLICATION-HALOAKANES AND HALOARENES-Warm up exercise
  1. What do you mean by an organometallic compound? Lead acetate [Pb(OCOCH...

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  2. How do you convert an alkyl halide into a hydrocarbon through the form...

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  3. Explain the observation: (CH3)(3)C CH(2)Clunderset(300^(@)C)overset(...

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  4. Explain why ether (solvent) used in the preparation of Grignard reagen...

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  5. Explain why haloarenes cannot be prepared from phenol.

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  6. The direct iodination of aromatic hydrocarbon is not a useful reaction...

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  7. Chlorination of ethylbenzene in the presence of light produces 1-chlor...

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  8. What is Raschig process?

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  9. What is Rasching process?

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  10. How is fluorobenzene prepared?

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  11. Carry out the following transformations: (i) Aniline to Bromobenzene

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  12. Carry out the following transformations: (ii) Ethylbenzenene to Styr...

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  13. Identify the products : (i)

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  14. Identify the products : (ii)

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  15. The dipole moment of fluorobenzene is lower than that of iodobenzene, ...

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  16. Arrange the various isomers of dichlorobenzene in the order of increas...

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  17. Explain why chlorobenzene is inert towards nucleophilic substitution r...

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  18. Identify A and B explain why they are formed.

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  19. Identify A and B explain why they are formed.

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  20. The hydrolysis of p-chloromitrobenzene requiries it to be heated with ...

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