Home
Class 12
CHEMISTRY
How do polar solvent help in the first s...

How do polar solvent help in the first step in `S_(N)1` mechanism?

Text Solution

Verified by Experts

In the first step i.e., rate determining step (r.d.s) of `S_(N)1` reaction, the substrate undergoes ionisation to form carbocation intermediate. Such ionisation process is favoured in presence of a polar solvent (i.e., solvent having high dielectric constant). Futhermore, especially the protic polar solvents stabilise the carbocation, thereby favouring the `S_(N)1` mechanism.
Promotional Banner

Topper's Solved these Questions

  • HALOAKANES AND HALOARENES

    CHHAYA PUBLICATION|Exercise Solved NCERT Examplar Problems: Matching type|6 Videos
  • HALOAKANES AND HALOARENES

    CHHAYA PUBLICATION|Exercise Solved NCERT Examplar Problems: Assertion-Reason Type|10 Videos
  • HALOAKANES AND HALOARENES

    CHHAYA PUBLICATION|Exercise Solved NCERT Examplar Problems: Multiple Choice Questions(More than One correct type)|11 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 6|10 Videos
  • HYDROCARBONS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 13|16 Videos

Similar Questions

Explore conceptually related problems

How do plants help in your household cooking?

Why polar protic solvent are suitable for S_(N)1 reaction?

How do the basophils help in body defence?

Which of the following compounds most readily undergoes solvolysis by S_(N)1 mechanism ?

What is variation? How do variations help in the origin of species in evolution?

Which of the following compounds most readily undergoes solvolysis by S_(N)1 mechanism-

If P^0 and P are the vapour pressure of the pure solvent and solution and n_1 and n_2 are the moles of solute and solvent respectively in the solution then the correct relation between P and P^0 is

Assertion : Tert- butyl methyl ether on cleavage with HI at 373 K gives tert-butyl iodide and methanol. Reason : The reaction occurs by S_(N^(1)) mechanism.

Tert-butyl chloride reacts with aqueous NaOH by S_(N^1) while n-butyl chloride reacts by S_(N^2) mechanism. Why?

Which of the following readily undergo nucleophilic substitution reaction by S_(N)1 mechanism in presence fo butanol-

CHHAYA PUBLICATION-HALOAKANES AND HALOARENES-Solved NCERT Examplar Problems: Short Answer Type
  1. Write down the structure and IUPAC name for neo-pentylbraomide.

    Text Solution

    |

  2. A hydrocarbon of molecular mass 72gcdot mol^(-1) gives a single monoch...

    Text Solution

    |

  3. Name the alkene which will yield 1-chloro-1-methylcyclohexane by its r...

    Text Solution

    |

  4. Which of the following haloalkanes reacts with aqueous KOH most easily...

    Text Solution

    |

  5. Why can aryl halides not be prepared by reaction of phenol with HCl in...

    Text Solution

    |

  6. Which of the following compounds would undergo S(N)1 reaction faster a...

    Text Solution

    |

  7. Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?

    Text Solution

    |

  8. Why is it necessary to avoid even traces of moisture during the use of...

    Text Solution

    |

  9. How do polar solvent help in the first step in S(N)1 mechanism?

    Text Solution

    |

  10. Write a test to detect the presence of double bond in a molecule.

    Text Solution

    |

  11. Diphenyls are potential threat to the environment. How are these produ...

    Text Solution

    |

  12. What are the IUPAC names of the insecticide DDt and benzenehexachlorid...

    Text Solution

    |

  13. Elimination reaction (especially -beta-elimination) are as common as t...

    Text Solution

    |

  14. How will you obtain monobromobenzene from aniline?

    Text Solution

    |

  15. Arly halides are extremely less reactive toward nucleophilic substitut...

    Text Solution

    |

  16. tert-Butylbromide reacts with aq.NaOH by S(N)1 mechanism while n-butyl...

    Text Solution

    |

  17. Predict the major product formed when HCl is added to isobutylene. Exp...

    Text Solution

    |

  18. Discuss the nature of C-X bond in the haloarenes.

    Text Solution

    |

  19. How can you obtain iodoethane from ethanol when no other iodine contai...

    Text Solution

    |

  20. Cyanide ion acts as an ambident nucleophilie. From which end it acts a...

    Text Solution

    |