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The S(N)2 reactivity with increase in st...

The `S_(N)2` reactivity________ with increase in steric hindrance.

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S_(N)2 reaction readily occurs in-

(A) With HBr, anisole forms bromobenzene and methyl alcohol. (R ) Br^(-) ion will combine with smaller group to avoid steric hindrance.

The S_(N)1 reactivity depends on the stability of the ______obtained in the rate-determining step.

The increasing order of S_(N)1 reactivity of the following compounds is- CH_(3)underset(CI)underset(|)CHCH_(2)CH_(3) , CH_(3)CH_(2)CH_(2)CI , p-CH_(3)O-C_(6)H_(4)-CH_(2)CI

Which one out of S_(N)1 and S_(N)2 reactions is more suceptible to steric effect and why?

The reactivity of compound Z with different halogens under appropriate conditions is given below (1)the steric effect of the halogen (2)the steric effect of tert-butyl group (3)the electronic effect of the phenolic group (4)the electronic effect of the tert-butyl group

S_(N)1 reactive of alkyl halides follows the order-

Arrange in the order of increasing S_(N)1 reactivity and explain the order: CH_(3)Cl,CH_(3)Br,CH_(3)CH_(2)Cl,(CH_3)_(2)CHCl .

CHHAYA PUBLICATION-HALOAKANES AND HALOARENES-Exercise - Fill in the blanks
  1. The IUPAC name iof BrCH(2)CH(2)CH(2)Cl is .

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  2. C(6)H(5)C(CH3)(2)Cl is an example of benzylic halide.

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  3. The CI atom in chlorobenzene is directing.

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  4. The bromoalkane obtained as the major product in free radical brominat...

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  5. CN^(Theta) is an nucleophile.

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  6. The central carbon atom in the transition state of an,, reaction is hy...

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  7. The compound obtained on alkaline hydrolysis of (S)-2-bromoctane is .

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  8. The S(N)1 reactivity depends on the stability of the obtained in the r...

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  9. The S(N)2 reactivity with increase in steric hindrance.

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  10. A chiral molecule is not on its mirror image.

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  11. CH(3)Cl does not undergo reaction while (CH3)(3)C Cl does not undergor...

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  12. Tendency of nucleophilic substitution reaction with increase in the no...

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  13. The C-CI bond in chlorobenzene is in length than the C-CI bond in ben...

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  14. Chlorobenzene is converted into phenol through the formation of (inter...

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  15. Ethanol & propanone react with I(2)//NaOH to form

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  16. Clorobenzene reacts with in the presence of conc. H(2)SO(4) to form DD...

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  17. Biphenyl is obtained when is heated with Cu-powder in a sealed tube.

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  18. Haloarenes are reactive than haloalkanes towards nucleophilic substit...

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  19. Freon-12 (CF(2)Cl(2)) is a widely used as

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