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Which one of each pair will not undergo ...

Which one of each pair will not undergo `S_(N)2` reaction and why?
(i) `(CH_3)_(3)C CH_(2)Cl, CH_(3)CH_(2)Cl`.

Text Solution

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Due to severe steric hindrance caused by 3 methyl groups at the `beta`-position, the first one is, in fact, inactive.
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Which one of each pair undergoes S_(N)I reaction readily and why? (i) CH_(2)=CHCH_(2)CH_(2)Cl, CH_(3)CH =CHCH_(2)Cl .

Which one of each pair of compounds will undergo S_(N)1 reaction readily and why? (ii) CH_(3)OCH_(2)Cl, CH_(3)OCH_(2)CH_(2)Cl .

Which one of each pair of compounds will undergo S_(N)1 reaction readily and why? (i) CH_(2)CH-CH_(2)CH_(2)Cl . CH_(3)CH=CHCH_(2)Cl .

Which halogen compound in each of the following pairs will reacts faster in S_(N)2 reaction: (ii) (CH_3)_(3)C-Cl or CH_(3)-Cl .

Which one of the pairs undergoes hydrolysis by aqueous KOH readily and Why? (ii) (CH_3)_(3)C Cl and (CD_3)_(3)C Cl .

Which one of the following pairs are more reactive in S_(N)2 reaction? Why? (iii) CH_(2)=CHBr and CH_(2)=CH-CH_(2)Br .

In which of the following two compounds S_(N)2 reaction is faster? Give reason. CH_(3)CH_(2)CH_(2)Cl and CH_(3)CH_(2)CH_(2)I .

Which of the compounds will react faster in S_(N)1 reaction with the OH^(-) ion? CH_(3)-CH_(2)-Cl or C_(6)H_(5)-CH_(2)-Cl .

CHHAYA PUBLICATION-HALOAKANES AND HALOARENES-Exercise - Short answer type questions
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  5. After standing in aqueous acid, (R)-2-butanol is found to have lost it...

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  7. Which one of each pair of compounds will undergo S(N)1 reaction readil...

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  8. In which reaction does recemisation occurs and why?

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  9. Prove that in S(N)2 reaction inversion of configuration takes place.

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  10. Arrange in increasing priority: -CH(2)CH(3), -CD(2)CH(3), -CH(3),-NH(2...

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  11. How can an asymmetric carbon be designated as R or S?

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  12. What is the necessary and sufficient condition for a molecule to show ...

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  13. What do you mean by enantiomers and diastereoisomers?

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  14. What do you mean by meso-compound and racemic modication? Explain why ...

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  15. What is Saytzef rule? Explain with an example.

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  16. Although haloalkanes can be prepared from alcohols, haloarenes cannot ...

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  18. Why is chlorobenzene inert towards S(N)1 and S(N)2 reactions?

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  19. Explain why the melting point of p-dichlorobenzene is higher than that...

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  20. Arrange chlorobenzene, p-chloronitrobenzene and m-chloronitrobenzene i...

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