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Which one of each pair of compounds will...

Which one of each pair of compounds will undergo `S_(N)1` reaction readily and why?
(i) `CH_(2)CH-CH_(2)CH_(2)Cl`.
`CH_(3)CH=CHCH_(2)Cl`.

Text Solution

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Second one as it forms resonance-stabilised allyl cation `(CH_3)CH=CH^(o+)CH_(2))`
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Which one of each pair of compounds will undergo S_(N)1 reaction readily and why? (ii) CH_(3)OCH_(2)Cl, CH_(3)OCH_(2)CH_(2)Cl .

Which one of each pair undergoes S_(N)I reaction readily and why? (i) CH_(2)=CHCH_(2)CH_(2)Cl, CH_(3)CH =CHCH_(2)Cl .

Which one of each pair will not undergo S_(N)2 reaction and why? (i) (CH_3)_(3)C CH_(2)Cl, CH_(3)CH_(2)Cl .

Which of the compounds will react faster in S_(N)1 reaction with the OH^(-) ion? CH_(3)-CH_(2)-Cl or C_(6)H_(5)-CH_(2)-Cl .

Which one of the pairs undergoes hydrolysis by aqueous KOH readily and Why? (i) C_(6)H_(5)CH_(2)Cl .

Which one of the following pairs are more reactive in S_(N)2 reaction? Why? (iii) CH_(2)=CHBr and CH_(2)=CH-CH_(2)Br .

In which of the following two compounds S_(N)2 reaction is faster? Give reason. CH_(3)CH_(2)CH_(2)Cl and CH_(3)CH_(2)CH_(2)I .

Which of the following compounds are optically active and why? (1) CH_(3)CHBrCH_(2)CH_(3) (2) (CD_(3))_(2)CHCH_(2)CH_(3)

Which of the following compounds will exhibit geometrical isomerism and why? (1) CH_(3)CH=C CI_(2) (2) CH_(3)CH=C CICH_(2)CH_(3) (3) CH_(2)=CH-CH_(2)

CHHAYA PUBLICATION-HALOAKANES AND HALOARENES-Exercise - Short answer type questions
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  2. After standing in aqueous acid, (R)-2-butanol is found to have lost it...

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  4. Which one of each pair of compounds will undergo S(N)1 reaction readil...

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  5. In which reaction does recemisation occurs and why?

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  6. Prove that in S(N)2 reaction inversion of configuration takes place.

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  7. Arrange in increasing priority: -CH(2)CH(3), -CD(2)CH(3), -CH(3),-NH(2...

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  8. How can an asymmetric carbon be designated as R or S?

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  9. What is the necessary and sufficient condition for a molecule to show ...

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  10. What do you mean by enantiomers and diastereoisomers?

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  11. What do you mean by meso-compound and racemic modication? Explain why ...

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  12. What is Saytzef rule? Explain with an example.

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  13. Although haloalkanes can be prepared from alcohols, haloarenes cannot ...

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  14. The dipole moment of chlorobenzene is lower than that of cyclohexyl ch...

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  15. Why is chlorobenzene inert towards S(N)1 and S(N)2 reactions?

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  16. Explain why the melting point of p-dichlorobenzene is higher than that...

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  17. Arrange chlorobenzene, p-chloronitrobenzene and m-chloronitrobenzene i...

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  18. How is chloroform preserved and why?

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  19. What are Freons? How can Freon-12 be prepared? Mention its uses and ph...

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  20. C(6)H(5)CH(2)CH(3)overset(Br(2)//hv)(rarr)Aoverset(NaCN)(rarr)B. Ident...

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