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CH(3)overset(O)overset(||)C CH(2)CH(2)CH...

`CH_(3)overset(O)overset(||)C CH_(2)CH_(2)CH_(2)Clunderset(/_\)overset(CH_(3)MgBr)rarrA`.
A is :

A

`CH_(3)underset(OH)underset(|)overset(OH)overset(|)C CH_(2)CH_(2)CH_(2)Cl`

B

`CH_(3)underset(O)underset(||)C CH_(2)CH_(2)CH_(2)CH_(3)`

C

D

Text Solution

Verified by Experts

The correct Answer is:
c
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CH_(3)-overset(O)overset(||)(C)-CH_(2)-Br

CH_(3)Br-CH_(2)-overset(O)overset(||)(C)-CH_(2)CH_(3)

The IUPAC name for CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-OH is :

An organic compound on reaction with O_(3) followed by Zn and H_(2)O gives CH_(3)-overset(O)overset(||)(C )-CH_(2)-CH_(2)-overset(O)overset(||)(C )-CH_(3) . The structures are:

CH_(3)-overset(O)overset(||)(CH)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-CH_(3) to CH_(3) - overset(OH)overset(|)(CH)-(CH_(2))_(3) - CH_(3) Above conversion can be achieved by :

CH_(3)-overset(O)overset(||)C-CH_(2)-CH_(2)-overset(O)overset(||)C-CH_(3)overset("dil.NaOH")rarrXoverset("Heat")rarrY The final product Y is

CH_(3)-overset(O)overset(||)(C)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CHOoverset(KOH,H_(2)O)to(A) , product A is

GRB PUBLICATION-ALCOHOL, ETHER AND EPOXY-STRAIGHT OBJECTIVE TYPE
  1. CH(3)overset(O)overset(||)C CH(2)CH(2)CH(2)Clunderset(/\)overset(CH(3)...

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  2. The compound which reacts fastest with Lucas reagent at room temperatu...

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  3. The compound which gives positive iodoform test is :

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  4. Diethyl ether on heating with concentrated HI gives two moles of :

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  5. An industrial method of preparation of methanol is :

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  6. HBr reacts fastest with :

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  7. Which of the following compounds is oxidized to prepare methylethyl ke...

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  8. In CH(3)CH(2)OH, the bond that undergoes hyteroytic cleavage most read...

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  9. The compound which gives the most stable carbonium on de

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  10. The products of combustion of an aliphatic thiol (RSH) at 298 K are :

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  11. The order of reactivety of the following alcohols towards conc. HCl is...

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  12. The reaction product of C(6)H(5)OCH(3)+Hioverset(/\)rarr…. Is :

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  13. Isobytyl magesium bromide with dry ether and absolute alcohol gives :

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  14. Which one of the following will most readily be dehydraed in acidic c...

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  15. The compound that will react most readily with NaOH to form methanol i...

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  17. The product of acid catalyzed hydration of 2-pheny1propene is

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  18. The best method to prepare cuclohexane from cyclohexanol is by using :

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  19. Compound on hydrolysis in aqueous acetone will be :

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  20. When phenyl magnesium bromide reacts with t-butanol the product would ...

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  21. In the reaction

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