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Fluorine has the highest electronegativi...

Fluorine has the highest electronegativity among the `ns^(2) np^(5)` group on the Pauling scale, but the elctron affinity of fluorine is less than that of chlorine because `:`

A

the atomic number of fluorine is less than that of chlorine

B

fluorine being the first member of the family behaves in an unusual manner

C

chlorine can accommodate an electron better than fluorine by utilising its vacant 3d-orbital

D

of small size, high electron density and an increased electron repulsion makes addition of an electron to fluorine less favourable than that in the case of chlorine in isolated stage

Text Solution

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The correct Answer is:
D
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GRB PUBLICATION-PERIODIC TABLE-D. Electron Gain Enthalpy (Electron Affinity)
  1. Which of the following will have the most negative electron gain entha...

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  2. Arrange S,O and Se in acending order of electron affinity?

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  3. Fluorine has the highest electronegativity among the ns^(2) np^(5) gro...

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  4. Which one of the following arrangements represents the correct order o...

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  5. For the process X(g) +e^(-) rarr X^(-)(g), DeltaH = x and X^(-)(g)...

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  6. Considering the elements F,CI,O and S, the correct order of their elec...

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  7. Which will have the maximum value of electron affinity O^(x),O^(y),O^(...

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  8. The electron gain enthalpies of halogens are as given below: F =- 33...

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  9. The formation of the oxide ion O((g))^(2-) requires first an exothermi...

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  10. For the electron affinity of halogens (with -ve sign), which of the fo...

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  11. Which of the following has minimum electron affinity?

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  12. The correct order of electron affinity is:

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  13. Which of the following statement is wrong?

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  14. Which one of the following statements is incorrect?

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  15. Which of the following electron affinity order is incorrect?

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  16. Select the equation is endothermic in nature?

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  17. Which one of the following statements is correct?

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  18. Electron affinity of first element in which of the following pairs is ...

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  19. The least stable in amongst the following is :

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  20. In which of the following arrangements the order is NOT according to t...

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