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Statement-1: The acidic strength order o...

Statement-1: The acidic strength order of hydra acids is `HF lt HCI lt HBr lt HI`
Statement-2: The E.N. of halogens are `F gt CI gt Br gt I`.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-2

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-2

C

Statement-1 is True, Statement-2 is False

D

Statement-1 is False, Statement-2 is True

Text Solution

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The correct Answer is:
B
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Statement 1: Acid strength increases in the order given as HFltltHClltltHBrltltHI . Statement 2: As the size of the elements F,Cl,Br,I increases down the group, the bond strength of HF,HCl,HBr and HI decreases and so the acid strength increases. In the light of the above statements, choose the correct answer from the options given below:

Statement-1 : Rate of electrophilic addition on alkene Higt HBr gt HCI gt HF. Statement-2 : Order of nucleophilicity I^(-) gt Br^(-) gt Cl^(-) gt F^(-).

Assertion Boiling point of halogen acids are in the order HF gtHBr gt HCI gt HI Reasoning Electronegativities are in the order F gt CI gt Br gt I .

The order HF lt HCl lt HBr lt HI corresponds to which of the following properties

Statement =-1: Nucleophilicity order in polar -protic solvent is I^(-)lt Br^(-)lt ^(-)lt F^(-) Statement -2: Due to bigger zise of I^(-) it is less sovlated in polar a-protic solvent.

GRB PUBLICATION-PERIODIC TABLE-Reasoning Type
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  2. Statement-1: Down the group, electronegativity decreases from B to TI....

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  3. Statement-1: Sc(Z = 21) is placed as d-block element. Statement-2: L...

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  4. Statement-1: Na^(+) and AI^(3+) are isoelectronic but the magnitude of...

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  5. Statement-1: The atomic radii of the elements of the oxygen family are...

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  6. Statement-1: Metallic character of first group metals increases down t...

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  7. Statement-1: Fluorine has a less negative electron gain enthalpy than ...

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  8. Statement-1: Fluorine forms only one oxoacid, HOF, Statement-2: Fluo...

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  9. Statement-1: Li and Mg shows diagonal relationship. Statement-2: Li...

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  10. Statement-1: The decreasing order of acidi character of CO(2),N(2)O(5)...

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  11. Statement-1: Oxidising property of F(2) is greater than Cl(2). State...

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  12. Statement-1: Generally, ionisation enthalpy increases from left to rig...

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  13. Statement-1: Boron has a smaller first ionisation enthalpy than beryll...

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  14. Assertion: Electron gain enthalpy always becomes less negative as we g...

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  15. Assertion: The first ionisation energy of Be is greater than that of B...

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  16. Statement-1: The acidic strength order of hydra acids is HF lt HCI lt ...

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  17. Statement-1: The decreasing order of acidic character of CO(2),N(2)O(5...

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  18. Statement-1: The ionisation potential of Sn is greater than Pb. Stat...

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  19. Statement-1: (I.E.)(n) of an atom is always greater than (I.E)(n-1) (n...

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  20. Statement-1: Nitrogen atom has higher ionization energy than fluorine ...

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