Home
Class 11
CHEMISTRY
The reducing effect of the nuclear charg...

The reducing effect of the nuclear charge by the inner electrons for on outer electron is termed aas shielding (or screening). As a result of shielding, the outer electrons in an atom always experience less nnuclear charge than the actual nuclear charge Z. The effective nuclear charge `(Z^(**))` as experienced by an electron is then obtained by subtracting the total shielding contributions from alll the other electrons (i.e., except the one under consideration) from the actual nuclear charge.
`Z^(**)=Z-sigma`
Where `sigma`=sum of the shielding contributions. The rules for estimating contributions to `sigma` are as follows (Slater's rule) Contribution to shielding by each electron is :
`|{:("Electron","All Higher","Same","Group","Group"le),("Grpoup","Group","Group",n-1,n-2),(1s," "0,0.30,-,-),((ns,sp)," "0,0.35,0.85,1.00),((nd)or(nf)," "0,0.35,1.00,1.00):}|`
According to Slater's treatment, the energy of an electron in nth shell of an atom having atomic number Z is given by the empirical equation
`E=-13.6((Z^(**))/(n))^(2)eV`
`Z^(**)` = effective nuclear charge
Which one among the following sets of ions represents the collection of isoelectronic species?

A

`S^(2-),CI^(-),K^(+),Ca^(2+),Sc^(3+)`

B

`N^(3-),O^(2-),Na^(+),Mg^(2+),AI^(3+)`

C

`K^(+),CI^(-),Mg^(2+),AI^(3+),Sc^(3+)`

D

(a) and (b) both

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • PERIODIC TABLE

    GRB PUBLICATION|Exercise Comprehension 2|1 Videos
  • PERIODIC TABLE

    GRB PUBLICATION|Exercise Comprehension 3|1 Videos
  • PERIODIC TABLE

    GRB PUBLICATION|Exercise Comprehension 1|1 Videos
  • NOMENCLATURE AND CLASSIFICATION

    GRB PUBLICATION|Exercise Subjective Type|24 Videos
  • PRACTICAL ORGANIC CHEMISTRY

    GRB PUBLICATION|Exercise Exercise 4 (Matrix match type )|1 Videos
GRB PUBLICATION-PERIODIC TABLE-Comprehension
  1. The reducing effect of the nuclear charge by the inner electrons for o...

    Text Solution

    |

  2. The reducing effect of the nuclear charge by the inner electrons for o...

    Text Solution

    |

  3. The reducing effect of the nuclear charge by the inner electrons for o...

    Text Solution

    |

  4. The amount of energy required to remove the most loosely bound electro...

    Text Solution

    |

  5. The amount of energy required to remove the most loosely bound electro...

    Text Solution

    |

  6. The minimum amount of energy which is required to remove an outermost ...

    Text Solution

    |

  7. The ionisation energy (IE(1)) of an atom is defined as the energy need...

    Text Solution

    |

  8. The ionisation energy (IE(1)) of an atom is defined as the energy need...

    Text Solution

    |

  9. An atom is assumed to tbe spherical in shape and thus, the size of ato...

    Text Solution

    |

  10. An atom is assumed to tbe spherical in shape and thus, the size of ato...

    Text Solution

    |

  11. An atom is assumed to tbe spherical in shape and thus, the size of ato...

    Text Solution

    |

  12. An atom is assumed to be spherical in shape and thus, the size of atom...

    Text Solution

    |

  13. Some of the properties which depend on electronic configuration elemen...

    Text Solution

    |

  14. Some of the properties which depend on electronic configuration elemen...

    Text Solution

    |

  15. In the modern period table, elements are arranged in order of increasi...

    Text Solution

    |

  16. In the modern period table, elements are arranged in order of increasi...

    Text Solution

    |

  17. In the modern periodic table, elements are arranged in order of increa...

    Text Solution

    |

  18. In the modern periodic table, elements are arranged in order of increa...

    Text Solution

    |

  19. Ionisation energies three hypothetical elements are given below (in kJ...

    Text Solution

    |

  20. Ionisation energies three hypothetical elements are given below (in kJ...

    Text Solution

    |