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A hydrated salt (x) gives golden yellow ...

A hydrated salt (x) gives golden yellow colour in flame test, given basic gas on treatement with `NaOH`, gives yellow ppt. on treatment with `(NH_(4))_(2)MoO_(4)` and `HNO_(3)`. It gives blue bead with `Co^(2+)` salt. The salt (x) is:

A

`NaAIO_(2).2H_(2)O`

B

`Na_(2)SO_(4).10H_(2)O`

C

`Na_(2)B_(4)O_(7).10H_(2)O`

D

`NaNH_(4)HPO_(4).4H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
D

`HPO_(4)^(2-)+3NH_(4)^(+) +12MnO_(4)^(2-)+23H^(+)`
`rarr underset("canary yellow ppt")((NH_(4))_(3)[P(Mo_(3)O_(10))_(4)]darr+12H_(2)O)`
`NaPO_(3)+CoO rarr NaCoPO_(4)` (Blue bead)
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GRB PUBLICATION-SALT ANALYSIS-B. Dry Tests/Colour/Solubility/Heating Effects
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  2. In Borax bead test the coloured ions give characteristic coloured bead...

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  3. A hydrated salt (x) gives golden yellow colour in flame test, given ba...

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  4. A,B, C and D are respectively:

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  5. If crimson flame is given when an inorganic mixture is tested by flame...

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  6. A brick red colour is imparted to Bunsen flame by a :

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  7. Which one of the following metal salts produced a blue coloured bead i...

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  8. Which one of the following cations will give a green coloured ash when...

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  9. What products are expected from the desproprtionation reactin of hypoc...

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  10. What is the colour of K^(+) through cobalt/double blue glass?

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  11. In the borax test of Co^(2+) , the blue colour of bead is due to the f...

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  12. Which of the following is not a preliminary test used to detect ions?

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  13. When copper nitrate is strongly heated, it is converted into

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  14. A chloride dissolves appreciably in cold water. When placed on platinu...

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  15. Which of the following does not give metal oxide on heating?

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  16. Which of the following metal bicarbonate will give metal oxide and CO(...

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  17. Which of the following metal nitrate will give metal and oxygen on hea...

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  18. Which of the following nitrate will give N(2)O on heating?

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  19. Which of the following ammonium salt will not give acid on heating?

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  20. Which of the following halide will not give halogen gas on heating?

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