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Which of the following statement(s) is (...

Which of the following statement(s) is (are) incorrect?

A

`Fe^(2+)` ions give a dark blue precipitate with potassium hexacyanidoferrate (III) solution

B

`Fe^(3+)` ions give intense blue precipitate with potassium hexacyanidoferrate (II) solution

C

`Fe^(3+)` ions give a brown colouration with potassium hexacyanidoferrate (III) solution.

D

`Fe^(2+)` ions give a deep red colouration with ammonium thiocyanate.

Text Solution

Verified by Experts

The correct Answer is:
D

`Fe^(3+) overset(SCN^(-))rarr Fe(SCN)_(3)darr` (Blood red colouration)
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GRB PUBLICATION-SALT ANALYSIS-I. IIIrd Group Cations
  1. Complex salt (X) gives....colour with AgNO(3). Complex (X) is formed b...

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  2. The cation which gives white precipitate of its hydroxide when treated...

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  3. Which of the following statement(s) is (are) incorrect?

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  4. CrCI(3) solution +Na(2)S solution rarr ppt (A) The correct formula and...

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  5. Which of the following is correct?

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  6. Fe^(2+) does not give prussian blue colour with K(4)[Fe(CN)(6)] but on...

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  7. When HNO(3) is added to sodium ferrocyanide, which of the following ob...

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  8. What product is formed by mixing the solution of K(4)[Fe(CN)(6)] with ...

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  9. Select the correct statement with respect to Fe^(3+) ions:

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  10. Which one of the following compounds on reaction with Na(2)O(2) in alk...

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  11. How do we differentiate between Fe^(3+) and Cr^(3+) in group III^(rd)?

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  12. A mixture of chlorides of copper, cadmium, chromium, iron and aluminiu...

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  13. CrO(4)^(2-)+H^(+) +H(2)O(2) overset("ether")rarr X +H(2)O Identify t...

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  14. FeCI(3)+K(3)[Fe(CN)(6)] +H(2)O(2) overset(OH^(-))rarr Precipitate. The...

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  15. CrCl(3) underset(NH(4)OH)overset(NH(4)Cl)to (A) underset(H(2)O)overset...

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  16. Give the correct order of initials T or F for following statements. Us...

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  17. Fe^(2+) and Fe^(3+) can be distinguished by

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  18. An aqueous solution of a salt X turns blood red on treatment with SCN^...

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  19. Ferric ion forms a prussian blue coloured ppt. due to

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  20. Which of these ions is expected to be coloured in aqueous solution? ...

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