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To increase significantly the concentrat...

To increase significantly the concentration of free `Zn^(2+)` ion is a solution of the complex ion `[Zn(NH_(3))_(4)]^(2+)`
`Zn^(2+) (aq)+4NH_(3) (aq) hArr [Zn(NH_(3))_(4)]^(2+) (aq)`
Add to the solution some:

A

`H_(2)O`

B

`HCI(aq)`

C

`NH_(3)(aq)`

D

`NH_(4)CI(aq)`

Text Solution

Verified by Experts

The correct Answer is:
B
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The EAN of Zn in [Zn(NH_(3))_(4)]^(2+) is

With the help of valence bond theory explain the bonding and shape of complex ion [Zn(NH_3)_4]^(2+) .

Zn^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(2)]^(+2), K_(1) = 2xx10^(-3) [Zn(NH_(3))_(2)]^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(4)]^(2+), K_(2) = 1.5xx10^(-3) Find out the instability constant?

What is the ratio of uncomplexed to complexed to complexed Zn^(2+) ion in a solution that is 10 M "in" NH_(3) . If the stability constant of [Zn(NH_(3))_(4)]^(2+) is 3xx10^(9) ?

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