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p-Amino-N,N-dimethylaniline is added to ...

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. the resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of the aqueous solution of Y with the reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z.
The compound Y is:

A

`MgCI_(2)`

B

`FeCI_(2)`

C

`FeCI_(3)`

D

`ZnCI_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

`X rarr Na_(2)S, Y rarr FeCI_(3), Z rarr Fe[Fe(CN)_(6)]`
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p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Y is

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound X is

p-Amino-N,N-dimethylaniline is added to a strongly acidic solution of X. The resulting solution is treated with a few drops of aqueous solution of Y to yield blue colouration due to the formation of methylene blue. Treatment of aqueous solution of Y with reagent potassium hexacyanoferrate (II) leads to the formation of an intense blue precipitate. The precipitate dissolves on excess addition of the reagent. Similarly, the treatment of the solution of Y with the solution of potassium hexacyanoferrate (III) leads to a brown colouration due to the formation of Z. Q. Compound Z is

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