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A colourless mixture of two salts (A) an...

A colourless mixture of two salts (A) and (B) excess is soluble in `H_(2)O`. Separately (A) turns blue litmus red and (B) turns red litmus blue. (A) given white precipitate with (B), which dissolves in excess of (B) forming (C). (A) when placed in moist air gives fumes and can form dimer. (A) gives white precipitate with `NH_(4)CI` and `NH_(4)OH` soluble in (B).(A) also gives white precipitate with `AgNO_(3)` soluble in `NH_(4)OH`.
(A) remains soluble in `H_(2)O` in presence of excess of (B). It is due to formation of :

A

`Na_(2)Zn(OH)_(2)`

B

`NaAI(OH)_(4)`

C

`Na_(2)Zn(OH)_(2)`

D

`AI_(2)O_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

`(A) rarr AICI`,
(B) `rarr NaOH, AI^(3+) +H_(2)O hArr AI(OH)^(2+) +H^(+)`
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GRB PUBLICATION-SALT ANALYSIS-Comprehension
  1. A coloured solution known to contain two metal ions of different group...

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  2. A coloured solution known to contain two metal ions of different group...

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  3. A colourless mixture of two salts (A) and (B) excess is soluble in H(2...

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  4. A colourless mixture of two salts (A) and (B) excess is soluble in H(2...

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  5. A colourless mixture of two salts (A) and (B) excess is soluble in H(2...

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  6. X +AgNO(3)rarr Y (white ppt.) Y is soluble in nitric acid an ammonia...

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  7. underset((16.8gm))("Solid"(A))overset(Delta)rarr underset((4.4gm))("Ac...

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  8. Acetic acid is added to the solution of sodium carbonate the gas evolv...

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  9. Acetic acid is added to the solution of sodium carbonate the gas evolv...

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  10. Blue compound Q is:

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  11. Solid A overset("on")underset("heating")rarr anhydrous A A on stron...

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  12. Yellow ppt. of compound (I) is insoluble in:

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  13. Type pf hybridization of complex (E):

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  14. Type of hybridisation of central atom of gas (B):

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  15. B +NaOH rarrDirty green ppt. overset(NH(3))underset(("excess"))rarr In...

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  16. The composition of C is/are:

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  17. E can acts as:

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  18. An aqueous solution of salt (P) gives white precipitate with barium ch...

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  19. The compound 'B' is having oxidation state of:

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  20. The hybridization of compound 'C' is:

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