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What is the principle of L.C.A.O. Discus...

What is the principle of L.C.A.O. Discuss the formation of bonding and antibonsing molecular orbital in the basis of this principle.

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What do you understand by bonding and antibonding molecular orbitals? Calculate the bond order for O_(2)^(+) and O_(2) .

According to MOT, two atomic orbitals overlap resulting in the formation of molecular orbital formed. Number of atomic orbitals overlapping together is equal to the molecule orbital formed. The two atomic orbital thus formed by LCAO (linear combination of atomic orbital) in the phase or in the different phase are known as bonding and antibonding molecular orbitals respectively. The energy of bonding molecular orbital is lower than that of the pure atomic orbitals by an amount Delta . This known as the stabilization energy. The enerby of antibonding molecular orbital in increased by Delta' (destabilisation energy). Q. Which of the following statements is not correct regarding bonding molecular orbitals?

According to MOT, two atomic orbitals overlap resulting in the formation of molecular orbital formed. Number of atomic orbitals overlapping together is equal to the molecule orbital formed. The two atomic orbital thus formed by LCAO (linear combination of atomic orbital) in the phase or in the different phase are known as bonding and antibonding molecular orbitals respectively. The energy of bonding molecular orbital is lower than that of the pure atomic orbitals by an amount Delta . This known as the stabilization energy. The enerby of antibonding molecular orbital in increased by Delta' (destabilisation energy). Q. How many nodal plane is present in sigma_(s and p) bonding molecular orbital ?

According to MOT, two atomic orbitals overlap relsulting in the formation of molecular orbital. Number of atomic orbitals overlapping together is equal to the molecular orbital formed. The two atomic orbital formed by LCAO (linear combination of atomic orbital) in the same phase or in the different phase are known as bonding and antibonding molecular orbitals respectively. theenergy of bonding molecular orbital is less than that of the pure atomic orbital by an amount Delta . this is known as the stabilization energy. the energy of antibonding molecular orbital is increased by 'Delta' (destabilisation energy) The bond order of N_(2)^(-) is equal to that of

DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE -COVALENT AND CO-ORDINATE BONDS
  1. What is bond stabilising energy ?

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  2. State three conditions which govern the combination of atomic arbitals...

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  3. What is the principle of L.C.A.O. Discuss the formation of bonding and...

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  4. A bonding molecular orbital has lesser energy than the corresponding a...

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  5. On the basic of the bond order, predivt which of the following species...

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  6. Explain the diamagnetic behaviour of F(2) molecule on the basis of mol...

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  7. Write the molecular orbital electronic configuration of peroxide and s...

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  8. Write the molecular orbital condiguration O(2),O(2)^(-)and o(2)^(2-) A...

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  9. With the help of molecular orbital theory predict which of the followi...

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  10. Explain why N(2) has a greater bond dissociation energy than N(2)^(+) ...

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  11. Which of the two peroxide ion or superoxide ion has larger bond length...

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  12. What is bond order? Discuss its significance.

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  13. Out of bonding and antibonding M.O, which is filled first and why?

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  14. Define bond order. How is it related to the stability of a molecule ?

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  15. How is bond order related to bond length and bond dissociation energy ...

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  16. Write the electronic jconfiguration of H(2)^(+) ion. Calculate the bon...

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  17. Which out of O(2)^(-)and O(2)^(2-) has higher bond order and why ?

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  18. Can a stable molecule have zero bond order ? Justify your answer.

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  19. How will you differentiate between bonding and anti bonding molecular ...

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  20. What are bonding and antibonding molecular arbitals ? Define bond orde...

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