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Four diatomic species are listed in dif...

Four diatomic species are listed in different sequence .Which of these represent the correct order of their increasing bond order?

A

`C_(2)^(2-) lt He_(2)^(+) lt NO lt O_(2)^(-)`

B

`He_(2)^(+) lt O_(2)^(-) lt NO ltC_(2)^(2-)`

C

`O_(2)^(-) lt NO lt C_(2)^(2-)ltHe_(2)^(+)`

D

`NOltC_(2)^(2-)ltO_(2)^(-)ltHe_(2)^(+)`

Text Solution

Verified by Experts

The correct Answer is:
B

`C_(2)^(2-)[sigma_(1s)]^(2)[sigma_(1s)^(**)]^(2)[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[pi_(2px)]^(2)=[pi_(2py)]^(2)[sigma_(2py)]^(2)`
`B.O.=1//2[10-4]=3`
`He_(2)^(+):[sigma_(1s)]^(2)[sigma_(1s)^(**)]^(1)`
`B.O.1//2[2-1]=1//2=0.5`
`NO: [sigma_(1s)]^(2)[sigma_(1s)^(**)]^(2)[sigma_(2s)]^(2)[sigma_(2s)^(**)][pi_(2px)]^(2)`
`=[pi_(2py)]^(2)[sigma_(2pz)]^(2)[pi_(2px)^(**)]^(1)`
`B.O.=1//2[10-5]=2.5`
`O_(2)^(-):[sigma_(1s)]^(2)[sigma_(1s)^(**)]^(2)[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[pi_(2px)]^(2)=[pi_(2py)]^(2)`
`[pi_(2px)^(**)]^(2)[pi_(2py)^(**)]^(1)`
`B.O.=1//2[10-7]=1.5`
Correct order : `He^(2+)ltO_(2)^(-)ltNO ltC_(2)^(2-)`
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DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE -MULTIPLE CHOICE QUESTIONS BANK (MCQB)
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  6. In which of the following pairs of molecules centreal atom is sp^(2) h...

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  7. Which of the following pairs is isostractural (i.e having the same sha...

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  8. Bond order of 1.5 is shown by:

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  9. Which of the following species contains three bond pair and one lone ...

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  10. The pair of specied having the same bond order is :

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  11. During change of O(2) to O(2)^(2-) ion, the electrons add on which of ...

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  12. Which one of the following molecules contains no pi - bond ?

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  14. Dipole-induced dipole interaction are present in which of the followin...

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  15. Which of the following is paramagnetic?

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  16. Which of the following species has plane tringular shape ?

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  17. Which one of the following is paramagnetic in nature ?

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  18. Which of the following pairs of ions are isoelectronic and also isostr...

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  19. The correct bond order in the following species is:

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  20. The total number of pi-bond electrons in the following structure is

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