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Which molecule/ion out of the following ...

Which molecule/ion out of the following does not contain unpaired electrons?

A

`N_(2)^(+)`

B

`O_(2)`

C

`O_(2)^(2-)`

D

`B_(2)`

Text Solution

Verified by Experts

The correct Answer is:
C

M.O. energy level diagrams of the different species are :
`N_(2)^(+)KK[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[pi_(2px)]^(2)[pi_(2py)]^(2)[sigma_(2pz)]^(1)`
`O_(2):KK[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[sigma_(2pz)]^(2)[pi_(2px)]^(1)`
`[pi_(2py)]^(2)[pi_(2px)^(**)]^(1)[pi_(2y)^(**)]^(1)`
`O_(2)^(2-):KK[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[sigma_(2pz)]^(2)[pi_(2x)]^(2)`
`[pi_(2py)][pi_(2px)^(**)]^(2)[pi_(2py)^(**)]^(2)`
`B_(2):KK[sigma_(2s)]^(2)[sigma_(2s)^(**)]^(2)[pi_(2px)]^(1)[pi_(2py)]^(1)`
`O_(2)^(2-)` ion has no unpaired electrons.
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DINESH PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE -MULTIPLE CHOICE QUESTIONS (TYPE -1)
  1. Which of the following species does not have tetraahedral geometry ?

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  2. Number of pi bonds and sigma bonds in the following structure is

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  3. Which molecule/ion out of the following does not contain unpaired elec...

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  4. In which of the following substances will hydrogen bond be strongest ?

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  5. In which of the following substances will hydrogen bond be strongest?

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  6. If the electronic configuration of an element is 1s^(2)2s^(2)2p^(2)3s^...

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  7. Which of the folowing angles corresponds to sp^(2) hybridisation ?

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  8. Stable from of A may be represented by the formula :

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  9. Stable from of C may be represented by the formula :

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  10. The molecular formula of the compound formed from B and C will be :

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  11. The bond between B and C will be

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  12. Which of the following orderof energies of molecular orbitals of N(2) ...

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  13. Which of the following statement is not correct from the view point of...

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  14. Which of the following options represents the correct bond order? Th...

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  15. The electronic configuration of the outer most shell of the most elect...

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  16. Amongst the following elements (whose electronic configuration an gi...

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  17. Which of the following attain the linear structure ?

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  18. CO is isoelectronic with

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  19. Which of the following species have the same shape?

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  20. Which of the following statements are correct about CO(3)^(2-)?

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