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Gases possess characteristic critical te...

Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the gas particles. Critical temperatures of ammonia and carbon dioxide are 405.5 K and 304.10 K respectively. Which of these gases will liquify first when you start cooling from 500 K to their critical temperature ?

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We have read that a gas gets liquefied when cooled below its critical temperature `(Tc)` . Upon cooling from 500 K, the critical temperature of ammonia `(405.5 K)` will be attained first. It will get liquefied first as compared to carbon dioxide for which critical temperature `(304.15 K)` is attained on further cooling.
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