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A saturated hydrocarbon having molecular...

A saturated hydrocarbon having molecular formula `C_(n)H_(2n+2)` diffuses through a porous membrane twice as fast as sulpjur dioxide.
Determine the molecualr mass of hydrocarbon and name it.

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To determine the molecular mass of the hydrocarbon and name it, we can follow these steps: ### Step 1: Understand the relationship between diffusion rates and molecular mass According to Graham's law of effusion, the rate of diffusion of a gas is inversely proportional to the square root of its molecular mass. This can be expressed as: \[ \frac{R_1}{R_2} = \sqrt{\frac{M_2}{M_1}} \] where \( R_1 \) and \( R_2 \) are the rates of diffusion of the two gases, and \( M_1 \) and \( M_2 \) are their respective molecular masses. ### Step 2: Set up the equation based on the problem In this case, we know that the hydrocarbon diffuses twice as fast as sulfur dioxide (SO2). Therefore, we can set: \[ \frac{R_{alkane}}{R_{SO2}} = 2 \] Let \( M_{SO2} \) be the molecular mass of sulfur dioxide, which is calculated as follows: \[ M_{SO2} = 32 \, \text{(S)} + 16 \, \text{(O)} \times 2 = 32 + 32 = 64 \, \text{g/mol} \] ### Step 3: Substitute into Graham's law Now substituting the known values into Graham's law: \[ 2 = \sqrt{\frac{64}{M_{alkane}}} \] ### Step 4: Square both sides to eliminate the square root Squaring both sides gives: \[ 4 = \frac{64}{M_{alkane}} \] ### Step 5: Rearrange to find the molecular mass of the alkane Rearranging the equation to solve for \( M_{alkane} \): \[ M_{alkane} = \frac{64}{4} = 16 \, \text{g/mol} \] ### Step 6: Determine the molecular formula of the hydrocarbon The molecular formula for a saturated hydrocarbon (alkane) is given by: \[ C_nH_{2n+2} \] ### Step 7: Set up the equation for molecular mass The molecular mass can also be expressed as: \[ M_{alkane} = 12n + (2n + 2) \cdot 1 = 12n + 2n + 2 = 14n + 2 \] Setting this equal to the molecular mass we found: \[ 14n + 2 = 16 \] ### Step 8: Solve for \( n \) Subtract 2 from both sides: \[ 14n = 14 \] Dividing both sides by 14 gives: \[ n = 1 \] ### Step 9: Write the molecular formula Substituting \( n \) back into the formula gives: \[ C_1H_{2(1)+2} = CH_4 \] ### Step 10: Name the hydrocarbon The hydrocarbon with the formula \( CH_4 \) is known as methane. ### Final Answer The molecular mass of the hydrocarbon is 16 g/mol, and the hydrocarbon is methane. ---

To determine the molecular mass of the hydrocarbon and name it, we can follow these steps: ### Step 1: Understand the relationship between diffusion rates and molecular mass According to Graham's law of effusion, the rate of diffusion of a gas is inversely proportional to the square root of its molecular mass. This can be expressed as: \[ \frac{R_1}{R_2} = \sqrt{\frac{M_2}{M_1}} \] ...
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DINESH PUBLICATION-STATES OF MATTER : GASES AND LIQUIDS-Practice
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  2. A gas having molecular mass 84.5 g mol^(-1) enclosed in a flask at 2...

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  3. 38.0 mL of moist nitrogen were collected at 27^(@)C and 0.98 bar press...

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  4. A given mass of gas occupies 919.0 mL of dry state at N.T.P. The mass...

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  5. What is the presser exerted by a mixture of 3.5 g of nitrogen and 2 g ...

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  6. A 10 L flask at 298 K contains a gaseous mixture of CO and CO(2) at a ...

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  7. A dry gas occupies 127 mL at N.T.P. If the same mass of the gas is col...

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  8. An open flask contains air at 27^(@)C Calculate the temperature at whi...

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  9. A 10 litre flask contains 0.2 mole of methane, 0.3 mole of hydrogen an...

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  10. At 25^(@)C and 760 mm of Hg pressure a gas occupies 600 mL volume. Wha...

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  11. What volume of O(2) at 2.00 atm pressure and 27^(@)C is requried to bu...

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  12. Butane (C(4)H(10)) gas burns in oxygen to give carbon dioxide and wate...

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  13. Calculate the volume of hydrogen librated at N.T.P. when 500 cm^(3) of...

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  14. What volume of air at N.T.P containing 21 % oxygen by volume is requi...

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  15. In an experiment 100 mL of hydrogen take 5 second and 100 mL of an unk...

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  16. 300 mL of nitrogen gas diffuse througha a porous memebrane in 100 seco...

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  17. A saturated hydrocarbon having molecular formula C(n)H(2n+2) diffuses ...

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  18. Calculate the molecular weight of a gas X which diffuses four times as...

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  19. A teacher enters a classroom from front door while a student from back...

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  20. The rate of diffusion of a gas X is sqrt(2) times that of Y. If the mo...

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