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Arrange the following carbocations in in...

Arrange the following carbocations in increasing order of stability and mention basis of the order suggested.
(i) `overset(o+)(C)H_(3)" "`(ii) `CH_(3)overset(o+)(C)H_(2)" "`(iii) `CH_(3)overset(o+)(C)HCH_(3)" "`(iv) `CH_(3)-underset(CH_(3))underset(|)overset(o+)(C)-CH_(3)`

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To arrange the given carbocations in increasing order of stability, we need to analyze each carbocation based on the concepts of inductive effect and hyperconjugation. The stability of carbocations is influenced by the number of alkyl groups attached to the positively charged carbon, as well as the presence of alpha hydrogens that can participate in hyperconjugation. ### Step-by-step Solution: 1. **Identify the Carbocations:** - (i) \( \overset{+}{C}H_3 \) (Methyl carbocation) - (ii) \( CH_3\overset{+}{C}H_2 \) (Ethyl carbocation) - (iii) \( CH_3\overset{+}{C}HCH_3 \) (Isopropyl carbocation) ...
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The stability of given free radicals in decreasing order is (i) CH_(3)-overset(.)(C)H_(2) , (ii) CH_(3)-Coverset(.)(H)-CH_(3) (iii) CH_(3)-underset(CH_(3))underset(|)overset(.)(C)-CH_(3) , (iv) overset(.)(C)H_(3)

Write stability order of following intermediates: (a)CH_(3) - overset(o+)CH_(2)" "(b)CH_(3) - overset(o+)CH - CH_(3) (c)CH_(3) - underset(CH_(3))underset(|)overset(CH_(3))overset(|)C o+

Arrange the following compound is decreasing order of macheophillic addection reation (I) CH_(3)-overset(O)overset(||)(C)-CH_(3) (II) CH_(3)-overset(O)overset(||)(C)-CI (III) CH_(3)-overset(O)overset(||)(C)-NH_(2) (Iv) CH_(3)-overset(O)overset(||)(C)-OH (V) CH_(3)-overset(O)overset(||)(C)-O-overset(O)overset(||)(C)-CH_(3)

Arrange the following increasing order of number of hyperconjugation structures. (I) CH_(3)-overset(.)(C)H-CH_(3) (II) CH_(3)-overset(CH_(3))overset(|)CH-overset(.)(C)H-CH_(3) (III) CH_(3)-overset(CH_(3))overset(|)underset(.)C-CH_(3)

Arrange the following in increasing order of stability (CH_(3))_(2)overset(o+)(C)-CH_(2)-CH_(3) (2) (CH_(3))_(3)overset(o+)(C) (3) (CH_(3))_(2)overset(o+)(C)H (4) CH_(3)overset(o+)(C)H_(2) (5) overset(o+)(C)H_(2)

CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(2)-underset(O)underset(||)(C)-NHCH_(3)

Arrange the following carbocations in order of increasing stability : {:(underset("(I)")((CH_(3))_(3)Coverset(+)CH_(2))", "underset("(II)")((CH_(3))_(3)overset(+)C)","),(underset("(III)")(CH_(3)CH_(2)overset(+)CH_(2))", "underset("(IV)")(CH_(3)overset(+)CHCH_(2)CH_(3))):}

Arrange the following compounds in decreasing order of nucleophilic addition reaction : CH_(3)-underset("I")overset(O)overset(||)C-CH_(3)" "CH_(3)-underset("II")overset(O)overset(||)C-Cl" "CH_(3)-underset("III")overset(O)overset(||)C-OH " "CH_(3)-overset(O)overset(||)underset(IV)C-NH_2 " "CH_(3)-overset(O)overset(||)C-underset(V)O-overset(O)overset(||)C-CH_(3)

Relative stabilities of the following carbocations will be in the order {:(overset(o+)(C)H_(3),CH_(3)overset(o+)(CH_(2)),overset(o+)(C)H_(2)OCH_(3),),((i)," "(ii)," "(iii),):}

DINESH PUBLICATION-ORGANIC CHEMISTRY - SOME BASIC PRINCIPLES & TECHNIOUES-PURIFICATION & CHARACTERISATION OF ORGANIC COMPOUNDS
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  3. In Kjeldahl's method, nitrogen is estimated as :

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  4. Two immiscible liquid present in a bottle can be separated by:

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  5. In sodium fusion test of organic compounds, the nitrogen in an organic...

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  6. Which of the following reagents is useful to separate benzoic acid fro...

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  7. In Duma's method, the gas collected in nitrometer is :

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  8. Anthracene is purified by :

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  9. 0.2 g of an organic compound on complete combustion produces 0.18 g of...

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  10. Which process is suitable for the purification of aniline ?

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  11. In the Lassaigne's test for the detection of sulphur, the purple colou...

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  12. For which of the following compounds will Lassaigne's test for nitroge...

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  13. The most satisfactory method to separate mixture of sugars is :

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  14. Lassaigne's extract is botted with dilute HNO(3) before testing for ha...

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  15. The purity of an organic solid is determined by :

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  16. Absolute alcohol is prepared by :

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  17. 0.32 g of an organic compound gave 0.233 g of BaSO(4). Determine the p...

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  18. Which is not used to purify organic solids ?

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  19. Chloroform and benzene form a pair of miscible liquids. These can be s...

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  20. During Lassaigne's test S and N present in an organic compound change ...

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  21. The best method to separate a mixture of ortho and para nitrophenol (1...

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