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Give the major products that are formed ...

Give the major products that are formed by heating each of the following ethers with HI
(i) `CH_(3)-CH_(2)-overset(CH_(3))overset(|)CH-CH_(2)-O-CH_(2)-CH_(3) " "` (ii) `CH_(3)-CH_(2)-CH_(2)-O-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH_(2)-CH_(3)`
(iii)

Text Solution

Verified by Experts

The reaction is guided by the principle that in case of unsymmetrical ethers, the hologen atom must bhe linked to the smaller alkyl group. Therefore , the major products of the reactions are :
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Give the major products that are formed by heating each of the following ethers with HI. (i) CH_(3)-CH_(2)-overset(CH_(3))overset("| ")(C )H-CH_(2)-O-CH_(2)-CH_(3) (ii) CH_(3)-CH_(2)-CH_(2)-O-overset(CH_(3))overset(|)underset(CH_(3))underset(|)(C )-CH_(2)-CH_(3) (iii)

CH_(3)-CH_(2)-CH_(2)-O-CH_(3) and CH_(3)-overset(CH_(3))overset(|)(C )H-O-CH_(3) are

Knowledge Check

  • CH_(3)-CH_(2)-CH_(2)overset(OH)overset(|)CH_(2) and CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)(OH)-CH_(3)

    A
    chain isomers
    B
    positional isomers
    C
    both (a) and (b)
    D
    none of these

  • The reaction, CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-ON a+CH_(3)CH_(2)Cl to CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-O-CH_(2)CH_(3) is called

    A
    Etard reaction
    B
    Gattermann-Kock reaction
    C
    Williamson synthesis
    D
    Williamson continuous etherification process

  • The reaction CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C )-ONa+CH_(3)CH_(2)ClrarrCH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C )-O-CH_(2)-CH_(3) is called

    A
    Gatterman - Koch reaction
    B
    Williamson synthesis
    C
    Williamson continuous etherification
    D
    Etard reaction

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    Write the commons of the following: CH_(3)-CH_(2)-CH_(2)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-NH_(2)

    CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

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    CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-CH=CH_(2)+HBr to A The structure of A is:

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