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(CH(3))(3)C-Br on reaction with sodium m...

`(CH_(3))_(3)C-Br` on reaction with sodium methoxide `(Na^("+)O^(-)CH_(3))` gives as the main product and not an ether.
Assign reason.

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To solve the question regarding the reaction of `(CH₃)₃C-Br` with sodium methoxide `(Na^+O^(-)CH₃)`, we need to analyze the reaction mechanism and the nature of the reactants involved. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are `(CH₃)₃C-Br` (tert-butyl bromide) and sodium methoxide `(Na^+O^(-)CH₃)`. 2. **Understand the Reaction Type**: ...
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(CH_(3))_(3)CoNa on reaction with CH_(3)Br will give

Anisole on reaction with HI gives phenol and CH_(3)-I as the main products and not iodobenzene and CH_(3)OH. Assign reasons.

(CH_(3))_(3)C-OCH_(3) on reaction with HI gives (CH_(3))_(3)C-I and CH_(3)-OH as the main products and not (CH_(3))_(3)C-OH and CH_(3)-I . Explain.

The main product of the reactin CH_(3)CH_(2)Br and AgCN is

An ethereal solution of an alkyl halide preferably the bromide of iodide, is treated with sodium 2R-X+2Na overset("Ether")toR-R+2NaX 2CH_(3)-Br+2Na overset("Ether")toCH_(3)-CH_(3)+2NaBr CH_(3)CH_(2)Br+2Na+CH_(3)Br overset("Ether")toCH_(3)CH_(2)-CH_(3)+2NaBr In this reaction, the product has new (C-C) bond with the same type of alkyl halide, the product has symmetery and this helps in deciding the nature of reacting halide. Intermediates are free radicals Formation of free radical is easiest in

Knowledge Check

  • (CH_(3))_(3)CoNa on reaction with CH_(3)Br will give

    A
    `(CH_(3))_(3)COC(CH_(3))_(3)`
    B
    `CH_(3)OCH_(3)`
    C
    `CH_(3)CH_(2)OCH_(2)CH_(3)`
    D
    `(CH_(3))_(3)COCH_(3)`

  • Assertion : (CH_(3))_(3)C-Br and CH_(3)CH_(2)O"N"a react to form (CH_(3))_(3)C-O-CH_(2)CH_(3) Reason : Good yields of ethers are obtained when tertalkyl halides are treated with alkoxides .

    A
    if both assertion and reason are true and the reason is the correct explanation of the assertion
    B
    If both assertion and reason are true but reason is not the correct explanation of the assertion.
    C
    If assertion is true but reason is false
    D
    If the assertion and reason both are false

  • The main product of the reactin CH_(3)CH_(2)Br and AgCN is

    A
    `CH_(3)CH_(2)CN`
    B
    `H_(3)C CH_(2)overset(+)N-=C^(-)`
    C
    `CH_(3)CH_(2)CH_(2)Br`
    D
    `H_(2)C=CH_(2)`
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