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Anisole on reaction with HI gives phenol...

Anisole on reaction with HI gives phenol and `CH_(3)-I` as the main products and not iodobenzene and `CH_(3)OH.` Assign reasons.

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(CH_(3))_(3)C-OCH_(3) on reaction with HI gives (CH_(3))_(3)C-I and CH_(3)-OH as the main products and not (CH_(3))_(3)C-OH and CH_(3)-I . Explain.

(CH_(3))_(3)C-Br on reaction with sodium methoxide (Na^("+)O^(-)CH_(3)) gives as the main product and not an ether. Assign reason.

Phenyl methyl ether (on anisole) reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol. Justify .

on reaction with CH_(3)OH in presence of H^(+) gives :

Cleavage of anisole with HI at 373 K gives phenol and CH_(3)I Reason : Due to resonance, O-C_(6)H_(5) bond is stronger than O-CH_(3) bond.

DINESH PUBLICATION-ETHERS-QUESTIONS FROM BOARD EXAMINATIONS
  1. Why are boiling points of ethrs lower than those of alcohols of compar...

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  2. How will you convert anisole to phenol ?

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  3. How do you account for the miscibility of ethoxyethane with water ?

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  4. Describe the mechanism for the formation of diethyl ether from ethanol...

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  5. Complete the following reaction : C(6)H(5)Ona+C(2)H(5)CIrarr

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  6. Write the IUPAC name of the compound : CH(3)-O-CH(2)-underset(CH(3))...

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  7. Write the names of reagents and equations for the preparation of follo...

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  8. State the products of the following reactions (i) CH(3)-CH(2)-CH(2)-...

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  9. Give a brief account of Williamson's synthesis.

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  10. Name the reagent used in the Friedel Craft's alkylation of anisole.

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  11. (CH(3))(3)C-OCH(3) on reaction with HI gives (CH(3))(3)C-I and CH(3)-O...

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  12. (CH(3))(3)C-Br on reaction with sodium methoxide (Na^("+)O^(-)CH(3)) g...

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  13. Complete the following : CH(3)-CH(2)-O-C(6)H(5)+HI("Conc.")rarr

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  14. Anisole on reaction with HI gives phenol and CH(3)-I as the main produ...

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  15. Write chemical equatio involved in Friedel Crafts acetylation of aniso...

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  16. Why is boiling point of n-butyl alcohol (118^(@)C) higher than that of...

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  17. Complete the reaction : CH(3)-underset(CH(3))underset(|)(CH(3))-O-CH...

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