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Select schemes A, B, C out of - I. ac...


Select schemes A, B, C out of -
I. acid catalysed hydration
II. HBO
III. Oxymercuration-demercuraton

A

I in all the cases

B

I,II,III

C

II,III,I

D

III,I,II.

Text Solution

Verified by Experts

The correct Answer is:
B

it is the correct asnwer. For details, consult section 12.6 (Industrial preparation or alcohols).
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Acid catalysed hydration of alkene give alcohol. In thic reaction addition of water takes place according to Markownikov's rule. Since intermediate carbocation is formed in this reaction, rearrangment of carbocation takes place. In oxymercuration-demercuration reaction hydration of alkene takes place according to markownikov's rule. Oxymercuratio-demercuration-dermercuration no rearrangement is possible. in hydroboration-oxidation hydration of alkene takes place according to anti marjownikow's addition. in HBO reaction rearrangement is not possible. both in oxymercuration-demercuation and hydroboration-oxidation, intermediate carbocation are not formed. Q. CH_(3)-C-=C-Hunderset(H_(2)O_(2)//OH^(-))overset((Sia)_(2)HB)toA, A is

Acid catalysed hydration of alkene give alcohol. In thic reaction addition of water takes place according to Markownikov's rule. Since intermediate carbocation is formed in this reaction, rearrangment of carbocation takes place. In oxymercuration-demercuration reaction hydration of alkene takes place according to markownikov's rule. Oxymercuratio-demercuration-dermercuration no rearrangement is possible. in hydroboration-oxidation hydration of alkene takes place according to anti marjownikow's addition. in HBO reaction rearrangement is not possible. both in oxymercuration-demercuation and hydroboration-oxidation, intermediate carbocation are not formed. Q. The product formed in the following reaction is: Pruduct

The relative rate of acid catalysed dehydration of following alcohols would be I. II. III. IV.

Predict the major product of acid catalysed dehydration of (i) 1-methylcyclohexanol and (ii) butan-1-ol

DINESH PUBLICATION-ETHERS-MULTIPLE CHOICE (MCQB)
  1. When ethyl alcohol is heated to 140^(@)C with conc. H(2)SO(4), the pro...

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  2. The major product formed on monobromination ((Br(2))/(FeBr(3))) of the...

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  3. The major organic product in the reaction CH(3)-O-CH(CH(3))(2)+HIrar...

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  4. In the reaction CH(3)overset(CH(3))overset(|)(C )H-CH(2)-O-CH(2)CH(3...

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  5. Which isomerism is shown by the following pairs ? CH(3)CH(2)CH(2)OH ...

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  6. No. of acyclic isomers of the compound having the molecular formula C(...

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  7. Among the following ethers, which one will produce methyl alcohol on t...

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  8. The following reaction is known by the name .

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  9. The reaction can be classified as:

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  10. The compound A on treatment with Na gives B, and with PCl(5) gives C. ...

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  11. Identifiy the final prodcut of the given reaction.

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  12. when reacted with two moles of CH(3)MgI followed by hydrolysis, the pr...

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  13. CH(3)-overset(CH(2)CH(3))overset(|)(CH)CH=CHCH(3)overset(H(3)O^(+))rar...

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  14. Select schemes A, B, C out of - I. acid catalysed hydration II. ...

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  15. Acidic dehydration of the following alcohols is in the order :

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  16. Which of the following is not cleaved by HI even at 525K ?

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  17. Rank the following subtances in order of increasing boiling points (lo...

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  18. The compound A will be :

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  19. In the given sequence of reactions The prodcut [D] can be :

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  20. Magnesium reacts with alkyl halide best in the solvent :

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