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WOLFF~KISHNER REDUCTION...

WOLFF~KISHNER REDUCTION

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METHODS OF PREPARATION OF ALCOHOLS|REDUCTION OF ALDEHYDES AND KETONES|MPV REDUCTION|HYDROLYSIS OF ESTER

REDUCTION TO ALKANES:

BY REDUCTIVE OZONOLYSIS:

H2/Pt,Ni,Pd Reduction Reaction, Rosenmund Reduction, Reduction OF Benzene and Examples

Reduction of Ore

Complete the following: a. 2PhCHO+NH_(2)NH_(2)rarr b. Reduction of PhCHO with the following: i. Tollens reagent ii. Zn//HCl iii. LAH iv. Clemmensen's reduction (Zn(Hg)//conc. HCl) v. Wolff-Kishner reduction (NH_(2)NH_(2)+Glycol+overset(Θ)(OH)) vi. Two moles of PhCHO with Zn + HCl

Methods of preparation(summary)-DIBAL-H || Cyanide || (CH3)2CD || kucheza reaction || stephen's reduction || properties-nucleophilic addition(NH2-2,NACN/HCN) || reduction(clemmensen,Wolff Kishner),oxidation(iodOForm) || aldol || cannizaro

Convert the following: How will you decide whether Clemmensen, Wolff-Kishner, or Raney Ni desulphurisation is the most efficacious for reducing a carbonyl compound?

Chemical Properties OF Carbonyl Compound || Reaction OF ammonia derivatives with carbonyl compound || Reduction :- Clemenson Reduction || Wolf kishner Reduction || Boulaut blank Reduction || Catalytic Reduction || Reduction OF Carbonyl to alcohol

Reduction OF Organic Compounds : -1) clemmensen reduction,20 wolf kishner reduction,3)mozingo reduction,4) HI/Redp,5) stephen''''''''s reduction,6)DIBAL-H,7) rosenmund''''''''s reduction,8) reduction OF nitro compounds

DINESH PUBLICATION-ALDEHYDES AND KETONES -Properties of Carbon
  1. How will you prepare benzaldehyde from toluene?

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  2. What is Tollen's reagent?

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  3. WOLFF~KISHNER REDUCTION

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  4. Complete the following reactions : (i) 2H-overset(O)overset(||)(C)-H...

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  5. Why is acetaldehyde more reactive than acetone towards nucleophilic a...

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  6. (CH(3))(3) C - CHO does not undergo aldol condensation due to

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  7. Complete the reaction

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  8. Out of CH(3)CH(2)COCH(2)CH(3) and CH(3)CH(2)CH(2)COCH(3) which gives i...

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  9. Complete the following reactions (i) CH(3)-overset(O)overset(||)(C)-...

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  10. Write the structure of the main products when ethanal (CH(3)CHO) react...

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  11. Arrange the following in order of increasing reactivity towards nucleo...

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  12. Discuss oxidation and reduction reactions of aldehydes and ketones.

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  13. How will you distinguish between the following ? C(6)H(5)-CH = CH-CO...

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  14. How will you distinguish between propanal and propanone?

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  15. Write chemical equation involved in Cannizzaro's reaction.

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  16. Why is acetaldehyde more reactive than acetone towards nucleophilic a...

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  17. How will you convert methanol into ethanal ?

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  18. How will you convert propanone to propene ?

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  19. Wrie test to distinguish (i) Ethanol and ethanal (ii) Propanal ...

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  20. (i) Explain Rosenmund reduction with equation (ii) How does propane ...

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