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Which of the following will undergo aldo...

Which of the following will undergo aldol condensation?

A

`CH_(2) = CHCHO`

B

`CH -= C CHO`

C

`C_(6)H_(5)CHO`

D

`CH_(3)CH_(2)CHO ?`

Text Solution

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The correct Answer is:
To determine which of the given compounds will undergo aldol condensation, we must first understand the requirements for this reaction. Aldol condensation typically occurs when a compound has at least one alpha-hydrogen adjacent to a carbonyl group (aldehyde or ketone). The presence of alpha-hydrogens allows for the formation of an enolate ion, which is crucial for the aldol reaction. ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds provided in the question. For this example, let's assume the options are: - A) CH2=CHCHO (Acrolein) - B) CH≡CCHO (Propyne) - C) C6H5CHO (Benzaldehyde) - D) C6H3CH2CHO (Substituted benzaldehyde) 2. **Check for Alpha-Hydrogens**: - **Option A (CH2=CHCHO)**: This compound has alpha-hydrogens on the carbon adjacent to the carbonyl (CHO) group. Therefore, it can undergo aldol condensation. - **Option B (CH≡CCHO)**: This compound also has alpha-hydrogens on the carbon adjacent to the carbonyl group. Thus, it can also undergo aldol condensation. - **Option C (C6H5CHO)**: Benzaldehyde has no alpha-hydrogens because the carbon adjacent to the carbonyl is part of the phenyl ring. Therefore, it cannot undergo aldol condensation. - **Option D (C6H3CH2CHO)**: This compound has alpha-hydrogens on the carbon adjacent to the carbonyl group, allowing it to undergo aldol condensation. 3. **Conclusion**: The compounds that can undergo aldol condensation are: - A) CH2=CHCHO (Acrolein) - B) CH≡CCHO (Propyne) - D) C6H3CH2CHO (Substituted benzaldehyde) ### Final Answer: The compounds that will undergo aldol condensation are: - A) CH2=CHCHO - B) CH≡CCHO - D) C6H3CH2CHO

To determine which of the given compounds will undergo aldol condensation, we must first understand the requirements for this reaction. Aldol condensation typically occurs when a compound has at least one alpha-hydrogen adjacent to a carbonyl group (aldehyde or ketone). The presence of alpha-hydrogens allows for the formation of an enolate ion, which is crucial for the aldol reaction. ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds provided in the question. For this example, let's assume the options are: - A) CH2=CHCHO (Acrolein) - B) CH≡CCHO (Propyne) - C) C6H5CHO (Benzaldehyde) ...
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DINESH PUBLICATION-ALDEHYDES AND KETONES -Multiple Choice
  1. In the reaction CH(3)CHO + CH(2)(COOH)(2) overset("Pyridine")underset(...

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  2. Benzaldehyde reacts with alcoholic KCN to give :

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  3. Which of the following will undergo aldol condensation?

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  4. Which type of isomerism is shown by pentaone?

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  5. Paraldehyde is formeed by the polymerisation of:

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  6. Aromatic aldehydes in the presence of CN^(-) ion give acyloins. The re...

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  7. Which of the following methods is used to convert ketone into hydrocar...

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  8. Oxidation of actaldehyde with SeO(2) form :

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  9. During reduction of carbonyl compounds by H(2)N NH(2) and KOH, the fir...

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  10. Which will not give formaldehyde on heating or upon distillation ?

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  11. When ethanal is heated with Fehling's solution, it gives a precipitate...

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  12. Acetone on heating with conc. H(2)SO(4) gives :

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  13. Which alkene on ozonolysis gives CH(3)CH(2)CHO and CH(3)underset(O)und...

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  14. Toluene reacts with chromyl chloride to form :

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  15. The reagent used for the separation of acetaldehyde from acetophenone ...

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  16. Which can be oxidized to the corresponding carbonyl compound?

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  17. The product of the following reaction are CH(3)C=C.CH(2)CH(3)=overse...

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  18. Nucleophilic addition reaction will be most favoured in

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  19. A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin w...

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  20. Which of the compounds with molecular formula C(5)H(10)yields acetone ...

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