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Which of the following on treatment with...

Which of the following on treatment with aqueus sodium hydroxide will give corresponding alcohol and acid?

A

`C_(6)H_(5)CHO`

B

`CH_(3)CH_(2)CH_(2)CHO`

C

`CH_(3)-overset(O)overset(||)(C)-CH_(3)`

D

`C_(6)H_(5)CH_(2)CHO`

Text Solution

Verified by Experts

The correct Answer is:
A

Benzaldehyde `(C_(6)H_(5)CHO)` without any `alpha`-hydrogen will take part in the Cannizzaro's reaction to form corresponding alcohol `(C_(6)H_(5)CH_(2)OH)` and acid `(C_(6)H_(5)COOH)`. The other three compounds have `alpha`-hydrogen and donot participate in the Cannizzaro's reaction.
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DINESH PUBLICATION-ALDEHYDES AND KETONES -Multiple Choice
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  10. Consider the following reaction : The product A is :

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  12. Reaction by which benzaldehyde cannot be prepared is :

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  13. Which one is most reactive towards nucleophilic addition reaction?

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  19. By which one of the following reactions ketones cannot be prepared ?

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