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In carbonyl compounds, the carbonyl grou...

In carbonyl compounds, the carbonyl group is polar as well as in `sp^(2)` hybridisation state. As a result, these compounds are highly reactive in nature and take part in the addition reactions. The mechanism of these reactions is nucleophilic in nature and is catalyseed in the weakly acidic medium. The extent of nycleophilic addition is influenced by two factors. These are steric effect of the groups attached to the carbonyl carbon atom. Both tend to decrease the reactivity of these compounds in the nuclephilic addition reactions.
Which of the following statement is not true for carbonyl `(gtC=O)` group?

A

The carbon atom of the carbonyl group is `sp^(2)`-hybridised

B

The `C = O` bond length is longer than `C = C` bond length.

C

The dipole moments of aldehydes and ketones lie in the range `2*3` to `2*8 D`.

D

The portion of the molecule immediately surrounding the carbonyl group is planar.

Text Solution

Verified by Experts

The correct Answer is:
B

`gtC = O` bond length `(123 "pm")` is shorter than `gtC = Clt` bond lengsth (134 pm).
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In carbonyl compounds, the carbonyl group is polar as well as in sp^(2) hybridisation state. As a result, these compounds are highly reactive in nature and take part in the addition reactions. The mechanism of these reactions is nucleophilic in nature and is catalyseed in the weakly acidic medium. The extent of nycleophilic addition is influenced by two factors. These are steric effect of the groups attached to the carbonyl carbon atom. Both tend to decrease the reactivity of these compounds in the nuclephilic addition reactions. Which of the following statements regarding carbonyl compounds is not correct?

The general order of reactivity of carbonyl compounds for nucleophilic addition reactions is -

The order of reactivity of carbonyl compounds for nucleophilic addition is

The reactivity of carbonyl compounds towards nucleophilic addition reaction gets affected by

Carbonyl compounds undergo nucleophilic addition because of :