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Assertion: (CH(3))(3)C COC(CH(3))(3) and...

Assertion: `(CH_(3))_(3)C COC(CH_(3))_(3)` and acetone can be distanguished by the reaction with `NaHSO_(3)`.
Reason : `HSO_(3)` is the nucleophile in bisulphite addition.

A

If both assertion and reason are correct and reason is correct explanation for assertion.

B

If both assertion and reason are correct and reason is not correct explanation for assertion.

C

If assertion is correct but reason is incorrect.

D

If assertion as well as reason are both incorrect.

Text Solution

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The correct Answer is:
B
Correct explanation `HSO_(3^-)` is a bulky nucleophile and experiences steric hindrane on attacking `(CH_(3))_(3)CO`. COC(CH_(3))_(3)` which is also a bulky carbonyl compound.
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