Home
Class 12
CHEMISTRY
Complete the following : (i) R-OH + PC...

Complete the following :
(i) `R-OH + PCl_(5) rarr`
(ii) `R-OH+PCl_(3) rarr`

Text Solution

Verified by Experts

(i) `R-OH+PCl_(5) rarr R-Cl+POCl_(3)+HCl`
(ii) `3R-OH+PCl_(3) rarr 3R-Cl+H_(3)PO_(3)`
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise PHENOLS|34 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise MCQB|74 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise PROBLEM FOR PRACTICE|39 Videos
  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Interger|5 Videos

Similar Questions

Explore conceptually related problems

Complete the following equation (i) Ag+PCl_(5)rarr (ii) CaF_(2)+H_(2)SO_(4)rarr

Complete and balance the following : (i) P_(4)O_(10)+PCl_(5)to (ii) NH_(3)+NaOCl to

Complete the reaction : CH_(3)COOH+PCl_(5)rarr

Express the rate of the following reactions: (a) PCl_(5) rarr PCl_(3) + Cl_(2) (b) 2NO_(2) rarr 2NO + O_(2) in terms of the concentrations of reactants and Products.

Complete and balance the following reactions : (i) P_4O_10 + PCl_5 rarr"___" (ii) NH_3 + NaOCl rarr "____" + NaCl + H_2 O (iii) Ca(PO_4)_3 + 4H_3PO_4 rarr"____" (iv) AgCl + NH_4OH rarr "_____" + "____" (v) Pb(NO_3)_2 overset (Delta)rarr PbO + "___" + "____" (vi) Mg + HNO_3 rarr "____" + "____" .

What happens when the following are heated ? (i) PCl_(5) (ii) H_(3)PO_(3) .

Consider the following reaction , {:(I. RCOOH +PCl_(5) to R COOCl+ POCl_(3)+CHl),(II. 3RCOOH+PCl_(5) to 3R COCl+H_(3)PO_(3)),(III. RCOOH+SOCl_(2) to RCOCl+SO_(2)+HCl):} Which of the abvoe reaction (s) is/are preferred for the synthesis of RCOCl ?

Complete and balance the following equation : P_4 O_10 + PCl_5 rarr .

DINESH PUBLICATION-ALCOHOLS AND PHENOLS-ASSIGNMENT
  1. Draw the structure and the name of the product when the following alco...

    Text Solution

    |

  2. Write the mechanism of hydration of ethene to yield ethanol.

    Text Solution

    |

  3. Alcohols are comparatively more soluble in water than hydrocarbons of ...

    Text Solution

    |

  4. Out of (a) CH(2)=CH-CH(2)OH (b) CH(2)=CH-CH(2)-CH(2)-OH, which will ...

    Text Solution

    |

  5. How will you convert methanol into ethanoic acid ?

    Text Solution

    |

  6. Explain esterification reaction.

    Text Solution

    |

  7. Explain the mechanism of the following reaction 2CH(3)CH(2)OH overse...

    Text Solution

    |

  8. Write any teo difference between methyl alcohol and ethyl alcohol.

    Text Solution

    |

  9. Write the structure of 4, 4-dimethylpentan-2-ol.

    Text Solution

    |

  10. Alcohols are comparatively more soluble in water than hydrocarbons of ...

    Text Solution

    |

  11. How will you prepare alcohols from alkyl halides and alkenes ? Write c...

    Text Solution

    |

  12. Give a chemical test to distinguish between methanol and ethanol.

    Text Solution

    |

  13. Which compound is formed when a secondary alcohol is oxidized ?

    Text Solution

    |

  14. Write the chemical reaction of enthanol with PCl(5) and PCl(3) separat...

    Text Solution

    |

  15. Complete the following : (i) R-OH + PCl(5) rarr (ii) R-OH+PCl(3) r...

    Text Solution

    |

  16. How will you convert : (i) Ethyl chloride to methoxyethane (ii) Ac...

    Text Solution

    |

  17. How will you distinguish between propan-2-ol and 2-methylpropan-2-ol ?

    Text Solution

    |

  18. Write the mechanism (using curved arrow notation) for the following re...

    Text Solution

    |

  19. Write the mechanism of dehydration of ethanol.

    Text Solution

    |

  20. Give the chemical tests to distinguish in the primary secondry and ter...

    Text Solution

    |