Home
Class 12
CHEMISTRY
In the reaction the electrophile invo...

In the reaction
the electrophile involved is

A

dichloromethyl cation `(underset(+)(C)HCl_(2))`

B

formyl cation `(underset(+)(C)HO)`

C

dichloromethyl anion `(underset(-)(C)HCl_(2))`

D

dichorocarbene `( : C Cl_(2))`

Text Solution

Verified by Experts

The correct Answer is:
D

It is an example of Reimer Tiemann reaction. The electrophile involved in the reaction is dichlorocarbene `( : C Cl_(2))` and is formed as follows :
`{:(CHCl_(3),+,OH^(-),hArr,overset(..)(C)Cl_(3)+H_(2)O),(,,,,darr-Cl^(-)),(,,,,:C Cl_(2)),(,,,,"Dichlorocarbene (electrophile)"):}`
For more details, consult section 16.
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise Comprehension|12 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise Straight Objective Type|24 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise PHENOLS|34 Videos
  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Interger|5 Videos

Similar Questions

Explore conceptually related problems

In the sulphonation of benzene, the electrophile involved is:

In Friedel-Carfts acylation reaction the electrophile is :

In a Friedel-Crafts reaction, the electrophile is:

In the Friedel-Crafts acylation reaction, the electrophile is

C_(6)H_(5)OH+CHCl_(3)+NaOH rarr salicyladehyde The electrophile involved in the above reaction is.

Reimer -Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicyladehydes as depicted below. The electrophile in this reaction is

DINESH PUBLICATION-ALCOHOLS AND PHENOLS-MCQB
  1. Which one is the most acidic compound?

    Text Solution

    |

  2. Identify the major product P, Q and R in the following sequence of rea...

    Text Solution

    |

  3. In the reaction the electrophile involved is

    Text Solution

    |

  4. The finalproduct of the reaction,

    Text Solution

    |

  5. In Reimer-Timann reaction, the reagent used is

    Text Solution

    |

  6. Arrange the following gem diols in decreasing order of stability :

    Text Solution

    |

  7. Which is the most suitable method for removing the traces of water fro...

    Text Solution

    |

  8. Trans-cyclohexane-1,2-diol can be obtained by the reaction of cyclohex...

    Text Solution

    |

  9. Among the following compounds which can be dehydrated very easily is:

    Text Solution

    |

  10. The best reagent to covert pent-3-en-2-ol into pent-3-en-2-one is :

    Text Solution

    |

  11. Acid catalysed hydration of alkenes except ethene leads to the formati...

    Text Solution

    |

  12. Among the following the one that gives pistive idoform test upon react...

    Text Solution

    |

  13. Pheny1 magesoium bromide reacts with methanol to give:

    Text Solution

    |

  14. In the following sequence of reactions, CH(3)CH(2)OHoverset(P+I(2))(...

    Text Solution

    |

  15. The major product obtanined on interaction of phenol with sodium hydr...

    Text Solution

    |

  16. The main product of the following reaction is C(6)H(5)CH(2)(OH)CH(CH(3...

    Text Solution

    |

  17. Which of the following has maximum p(Ka) value ?

    Text Solution

    |

  18. The final product(s) of the reaction is (are) :

    Text Solution

    |

  19. Ethyl alcohol cannot be used as solvent for methyl magnesium iodide be...

    Text Solution

    |

  20. Which of the following give positive iodoform test ? (1) Ethanol, (2...

    Text Solution

    |