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Complete the following reaction...

Complete the following reaction

A

`C_(6)H_(5)OC_(2)H_(5)`

B

`C_(2)H_(5)OC_(2)H_(5)`

C

`C_(6)H_(5)OC_(6)H_(5)`

D

`C_(6)H_(5)I`.

Text Solution

Verified by Experts

The correct Answer is:
B

`C_(6)H_(5)O^(Ɵ)` ion formed by the abstraction of `H^(+)` from phenol by `C_(2)H_(5)O^(Ɵ)` ion is expected to attack `C_(2)H_(5)-I`. But as a weaker nucleophile as compared to `C_(2)H_(5)O^(Ɵ)` ion due to the presence of electron withdrawing `C_(6)H_(5)` group, it does not attack. Rather `C_(2)H_(5)O^(Ɵ)` ion attacks `C_(2)H_(5)-I` to form diethyl ether.
`C_(2)H_(5)O^(Ɵ)+C_(2)H_(5)-I rarr C_(2)H_(5)-O-C_(2)H_(5)+I^(-)`
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DINESH PUBLICATION-ALCOHOLS AND PHENOLS-Straight Objective Type
  1. The reaction of HBr with gives

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  2. The most unlikely representation of resonance structure of p-nitrophen...

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  3. Which of the following will be most readily dehydrated in acidic condi...

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  4. Propan-1-ol and propan-2-ol can be best distinguished by :

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  5. Complete the following reaction

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  6. 2-Phenylpropene on acidic hydration gives:

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  7. When phenyl magnesium bromide reacts with tert butanol, which of the f...

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  8. (I) 1,2-Dihydroxy benzene (II) 1,3-Dihydroxy benzene (III) 1,4-Dih...

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  9. The major product U in the following reaction is

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  10. Compounds which are used for the denaturation of alcohols are :

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  11. Primary secondary and tertiary alcohols are distinguised by

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  12. Alcohols can be prepared by which of the following methods ?

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  13. Grignard's reagents give alkanes by reaction with :

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  14. Isobutyl alcohol cannot be obtained by the reaction between

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  15. Phenol is less acidic than

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  16. When phenol reactes with CHCl(3) and NaOH followed by acidification, ...

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  17. In the reaction the intermediate(s) is/are:

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  18. Identify the binary mixture(s) that can be separated into individual c...

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  19. In the following reaction, the product(s) formed is (are) :

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  20. The correct statement(s) about the following reaction sequence is (are...

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