Home
Class 11
CHEMISTRY
The half-life periof for catalystic deco...

The half-life periof for catalystic decompoistion of `AB_(3)` at `50 mm` is found to be `4` hr and at `100 mm` it is `2.0 hr`. The order of reaction is

A

3

B

1

C

2

D

0

Text Solution

Verified by Experts

The correct Answer is:
C

`t_(1//2)prop(1)/((P)^(n-1))` where n is order
Now `((t_(1//2))_(1))/((t_(1//2))_(2))=((p_(2))/(p_(1)))^(n-1)`
or `(2)/(4)=((50)/(100))^(n-1)`
or `(1)/(2)=((1)/(2))^(n-1)or n-1=1or n=1`.
Promotional Banner

Topper's Solved these Questions

  • RATES OF REACTIONS AND CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Revision Question|168 Videos
  • RATES OF REACTIONS AND CHEMICAL KINETICS

    DINESH PUBLICATION|Exercise Selected Straight|49 Videos
  • PHYSICAL AND CHEMICAL EQUILIBRIA

    DINESH PUBLICATION|Exercise ULTIMATE PREPARATORY PACKAGE|13 Videos
  • REDOX REACTIONS

    DINESH PUBLICATION|Exercise Reasoning Type Questions|4 Videos

Similar Questions

Explore conceptually related problems

The half life period for catalytic decomposition of AB_(3) at 50 mm is found to be 4 hrs and at 100 mm it in 2 hrs. The order of reaction is :

The half life period for catalytic decomposition of XY_3 at 100 mm is found to be 8 hrs and at 200 mm it is 4 hrs. The order of reaction is

The half -lie period for the decomposition of AB_(2)(g) at 100mm pressure is 10min and at 200mm pressure is 5 min, the order of reaction is

Half life period of 2 nd order reaction is

The half-life periof of a first order reaction is…………..of initial concentration.

At 380^(@)C , the half-life periof for the first order decompoistion of H_(2)O_(2) is 360 min . The energy of activation of the reaction is 200 kJ mol^(-1) . Calculate the time required for 75% decompoistion at 450^(@)C .

The half-life for a reaction at initial concentration of 0.5 and 1.0 "mole litre"^(-1) are 200 sec and 100 sec respectively. The order of the reaction is

DINESH PUBLICATION-RATES OF REACTIONS AND CHEMICAL KINETICS-Ultimate Preparatory Package
  1. The half-life periof for catalystic decompoistion of AB(3) at 50 mm is...

    Text Solution

    |

  2. The general expression for half life period of an nth order reaction ...

    Text Solution

    |

  3. The general expression for rate constant k for an nth order reaction ...

    Text Solution

    |

  4. Which of the following will react faster (i.e., produce more product m...

    Text Solution

    |

  5. The hydrolysis of methyl acetate in alkaline solution CH(3)COOH(3)+O...

    Text Solution

    |

  6. A viral preparation was inactivated in a chemical bath. The inactivate...

    Text Solution

    |

  7. If initial concentration of ethyl acetate is 0.50 M it is hydrolysed w...

    Text Solution

    |

  8. The hypothetical reaction A+B rarr C is first order with respect to ea...

    Text Solution

    |

  9. A certain reaction A+B rarr C is first order with respect to each reac...

    Text Solution

    |

  10. The decomposition of N(2)O into N(2) and O in the presence of gaseous ...

    Text Solution

    |

  11. The rate constant for the first order decomposition of ethylene oxide ...

    Text Solution

    |

  12. A substance X decomposes in solution following the first order kinetic...

    Text Solution

    |

  13. In a second order reaction, first order in each reactant A and B, whic...

    Text Solution

    |

  14. For a first order reaction, the ratio of time for the completion of 99...

    Text Solution

    |

  15. For the reaction R rarr P when concentration of R is made double the r...

    Text Solution

    |

  16. The chemical reaction 2O(3) overset(k(1))rarr 3O(2) proceeds as follow...

    Text Solution

    |

  17. The concentration of a reactant in solution falls from (i) 0.5 M to 0....

    Text Solution

    |

  18. In a particular reaction t(1//2) was found to increase 16 times when i...

    Text Solution

    |

  19. For a zero order reaction a graph of conc. (along Y axis) and time (al...

    Text Solution

    |

  20. The rate constant of a zero order reaction is 0.2 mol dm^(-3) "min"^(-...

    Text Solution

    |

  21. For a hypothetical reaction R rarr P the rate constant is 2944.06 s^(-...

    Text Solution

    |