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The decomposition of NH(3) on platinum s...

The decomposition of `NH_(3)` on platinum surface is zero order reaction the rate of production of `H_(2)` is `(k=2.5xx10^(-4) M s^(-1))`

A

`2.5xx10^(-4) M s^(-1)`

B

`1.25 xx 10^(-4) M s^(-1)`

C

`3.75 xx10^(-4) M s^(-1)`

D

`5.0 xx10^(-4) M s^(-1)`

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The correct Answer is:
To solve the problem regarding the decomposition of ammonia (NH₃) on a platinum surface, we need to follow these steps: ### Step 1: Understand the Reaction The decomposition of ammonia can be represented by the following balanced chemical equation: \[ 2 \text{NH}_3 \rightarrow \text{N}_2 + 3 \text{H}_2 \] ### Step 2: Identify the Order of Reaction The problem states that the decomposition of NH₃ is a zero-order reaction. In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactants. ### Step 3: Write the Rate Law For a zero-order reaction, the rate law can be expressed as: \[ R = k \] Where: - \( R \) is the rate of the reaction, - \( k \) is the rate constant. Given that \( k = 2.5 \times 10^{-4} \, \text{M s}^{-1} \), we can state: \[ R = 2.5 \times 10^{-4} \, \text{M s}^{-1} \] ### Step 4: Relate the Rate of Production of H₂ to the Rate of Reaction From the balanced equation, we see that 3 moles of H₂ are produced for every 2 moles of NH₃ decomposed. Thus, the rate of formation of H₂ can be related to the rate of the reaction: \[ R_{\text{H}_2} = \frac{3}{2} R \] ### Step 5: Calculate the Rate of Production of H₂ Substituting the value of \( R \) into the equation gives: \[ R_{\text{H}_2} = \frac{3}{2} (2.5 \times 10^{-4}) \] \[ R_{\text{H}_2} = \frac{3 \times 2.5}{2} \times 10^{-4} \] \[ R_{\text{H}_2} = \frac{7.5}{2} \times 10^{-4} \] \[ R_{\text{H}_2} = 3.75 \times 10^{-4} \, \text{M s}^{-1} \] ### Final Answer The rate of production of H₂ is: \[ R_{\text{H}_2} = 3.75 \times 10^{-4} \, \text{M s}^{-1} \] ---

To solve the problem regarding the decomposition of ammonia (NH₃) on a platinum surface, we need to follow these steps: ### Step 1: Understand the Reaction The decomposition of ammonia can be represented by the following balanced chemical equation: \[ 2 \text{NH}_3 \rightarrow \text{N}_2 + 3 \text{H}_2 \] ### Step 2: Identify the Order of Reaction The problem states that the decomposition of NH₃ is a zero-order reaction. In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactants. ...
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