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The half-life of a reaction is halved as...

The half-life of a reaction is halved as the initial concentration of the reaction is doubled. The order of the reaction is

A

0.5

B

1

C

2

D

0

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The correct Answer is:
To determine the order of the reaction based on the information provided, we can analyze the relationship between half-life and concentration for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Half-Life**: The half-life (T₁/₂) of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. 2. **Given Information**: We are told that when the initial concentration of the reactant is doubled, the half-life of the reaction is halved. This indicates a specific relationship between half-life and concentration. 3. **Analyzing Zero-Order Reactions**: - For a zero-order reaction, the half-life is given by the formula: \[ T_{1/2} = \frac{[A]_0}{2k} \] - Here, T₁/₂ is directly proportional to the initial concentration \([A]_0\). If we double \([A]_0\), T₁/₂ would also double, which contradicts the given information. Therefore, the reaction cannot be zero-order. 4. **Analyzing First-Order Reactions**: - For a first-order reaction, the half-life is given by: \[ T_{1/2} = \frac{0.693}{k} \] - The half-life for a first-order reaction is independent of the concentration. Doubling the concentration does not affect the half-life. Hence, this reaction cannot be first-order either. 5. **Analyzing Second-Order Reactions**: - For a second-order reaction, the half-life is given by: \[ T_{1/2} = \frac{1}{k[A]_0} \] - In this case, the half-life is inversely proportional to the initial concentration. If we double the concentration, the half-life will be halved, which is consistent with the information given in the question. 6. **Conclusion**: Since the only scenario that matches the condition where the half-life is halved when the concentration is doubled is the second-order reaction, we conclude that the order of the reaction is **second order**. ### Final Answer: The order of the reaction is **second order**.

To determine the order of the reaction based on the information provided, we can analyze the relationship between half-life and concentration for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Half-Life**: The half-life (T₁/₂) of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. 2. **Given Information**: ...
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DINESH PUBLICATION-RATES OF REACTIONS AND CHEMICAL KINETICS-Revision Question
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  2. The unit of second order reaction rate constant is

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  3. The half-life of a reaction is halved as the initial concentration of ...

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  4. The rate constant of a reaction at temperature 200 K is 10 times less ...

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  5. Which one of the following equation is correct forr the reaction : N(2...

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  6. For a chemical reaction ……. Can never be a fraction

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  7. 75% of a first-order reaction was completed in 32 minutes, when was 50...

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  8. The time taken for the completion of 3/4 of a first order reaction is

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  9. The rate constant k, for the reaction N(2)O(5)(g) rarr 2NO(2) (g) + (1...

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  10. The rate of first-order reaction is 1.5 xx 10^(-2) M "min"^(-1) at 0.5...

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  11. The velocity constant of a reaction at 290 K was found to be 3.2 xx 10...

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  12. The reaction, 2SO(2(g)) + O(2(g))hArr2SO(3(g)) is carried out in a 1 d...

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  13. The activation energy for most of the reactions is approximately "50 k...

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  14. Which is correct about zero order reaction ?

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  15. The half-life of 2 sample are 0.1 and 0.4 seconds. Their respctive con...

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  16. In a first order reaction, the concentration of the reactant decreases...

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  17. The rate equation for the reaction 2A+B rarr C is found to be: rate = ...

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  18. For the reaction : 2A +B rarr C +D, measurement of the rate of the rea...

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  19. A first-order reaction was started with a decimolar solution of the re...

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  20. A substance undergoes first order decomposition. The decomposition fol...

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