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The rate constant of a reaction at tempe...

The rate constant of a reaction at temperature 200 K is 10 times less than the rate constant at 400 K. What is the activation energy `(E_(a))` of the reaction ? (R = gas constant)

A

1842.4 R

B

921.2 R

C

460.6 R

D

230.3 R

Text Solution

Verified by Experts

The correct Answer is:
B

`"log"(k_(2))/(k_(1))=(E_(a))/(2.303)[(1)/(T_(1))-(1)/(T_(2))]`
`"log"(1)/(10)=(E_(a))/(2.303R)[(1)/(400)-(1)/(200)]`
`-1 = E_(a) [(1-2)/(400)]`
`E_(a) = 400 xx 2.303 R`
`= 921.2 R`
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