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What will be the emf for the given cell ...

What will be the emf for the given cell ?
`Pt|H_(2)(g,P_(1))|H^(+)(aq)|H_(2)(g,P_(2))|Pt`

A

`(RT)/(F) "In"(P_(1))/(P_(2))`

B

`(RT)/(2F) "In"(P_(1))/(P_(2))`

C

`(RT)/(F) "In"(P_(2))/(P_(1))`

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B

KLHS, `H_(2)(P_(1)) hArr 2H^(+) + 2e^(-)` Oxidation
`("RHS" , 2H^(+)+2e^(-)hArrH_(2)(P_(2))"Reduction")/(H_(2)(P_(2))hArrH_(2)(P_(2)))`
`therefore E=E^(@)-(RT)/(nF) "In"(P_(2))/(P_(1))=0+(RT)/(2F) "In"(P_(1))/(P_(2))`
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