Home
Class 11
CHEMISTRY
For a hypothetical reaction, the followi...

For a hypothetical reaction, the following kinetic data suggested that the overall order of this reaction is
`{:("[A]",[B],[C]),(mol" "dm^(-3),mol" "dm^(-3),mol" " dm^(-3) s^(-1)),(2.0,1.0,1.0),(2.0,4.0,2.0),(1.0,4.0,1.0):}`

A

3

B

1.5

C

1

D

0.5

Text Solution

Verified by Experts

The correct Answer is:
B
Let rate of reaction , `r=[A]^(a) [B]^(b)`
`1=(2)^(a)(1)^(b)" "…(i)`
`2=(2)^(a)(1)^(b)" "…(ii)`
`1=(1)^(a)(4)^(b)" "…(iii)`
Dividing (ii) by (i)
`((2)^(a)(4)^(b))/((2)^(a)(1)^(b))=(2)/(1)`
`4=2 to b=1//2`
Dividing (ii) by (iii)
`((2)^(a)(4)^(b))/((1)^(a)(4)^(b))=(2)/(1)`
`2^(a) = 2 implies a=1`
`therefore` Rate law expression is , `r=[A][B]^(1//2)`
Order of reaction `=1+(1)/(2)=(3)/(2)=1.5`
Promotional Banner

Topper's Solved these Questions

  • NUCLEAR AND RADIO CHEMISTRY

    DINESH PUBLICATION|Exercise Unit Test 4|40 Videos

  • NOMENCLATURE OF ORGANIC COMPOUNDS

    DINESH PUBLICATION|Exercise MCQs|13 Videos

  • ORGANIC CHEMISTRY - SOME BASIC PRINCIPLES & TECHNIOUES

    DINESH PUBLICATION|Exercise PURIFICATION & CHARACTERISATION OF ORGANIC COMPOUNDS|38 Videos

Similar Questions

Explore conceptually related problems

Calculate the order of the reaction in A and B :- {:(A,,,B,,,Rate),(("mol"//1),,,("mol"//1),,,),(0.05,,,0.05,,,1.2xx10^(-3)),(0.10,,,0.05,,,2.4xx10^(-3)),(0.05,,,0.10,,,1.2xx10^(-3)):}

For a hypothetical reaction A + B rarr C , suggest the rate law and order form the following data: |{:("Experiment",[A] (mol L^(-1)),[B] (mol L^(-1)),"Refer of reaction" (mol L^(-1) s^(-1)),),(I,0.25,0.25,3.0 xx 10^(-3),),(II,0.50,0.25,6.0 xx 10^(-3),),(III,0.50,0.50,1.20 xx 10^(-2),):}|

For the reaction : 2A + B rarr C + D , measurement of the rate of the reaction at varying concentrations are given below: {:("Trial No.",[A],[B],"Rate in mol L"^(-1)s^(-1)),(1,0.010,0.010,2.5),(2,0.010,0.020,5.0),(3,0.030,0.020,45.0):} The overall order of the reaction is :

In data given below. {:(,[A],[B],"rate"),(,mol//L,mol//L,mol L ^(-1)s^(-1)),(a., 0.02,1.2,3.0xx10^(-3)),(b.,0.04,2.4,6.0xx10^(-3)):} The reaction may be

For the reaction 2A + B to C, rate of disappearance of A 0.076 mols^-1. What is the rate of the overall reaction?

For the hypothetical reaction 2A + B rarr Products following data obtained: |{:("Experiment number","Initial conc of (A)" (mol L^(-1)),"Initial conc of (B)" (mol L^(-1)),"Initial rate mol" L^(-1) s^(-1),),(1,0.10,0.20,3 xx 10^(2),),(2,0.30,0.40,3.6 xx 10^(10^(3)),),(3,0.30,0.80,1.44 xx 10^(4),),(4,0.10,0.40,...,),(5,0.20,0.60,...,),(6,0.30,1.20,...,):}| Find out how the rate of the reaction depends upon the concentration of A and B and fill in the blanks given in the table.

The following data are obtained for a reaction, X+Yrarr"Products" . {:("Expt. ",[X_(0)]//"mol ",[Y_(0)]//"mol ","rate/mol L"^(-1)s^(-1)),(1,0.25,0.25,1.0xx10^(-6)),(2,0.50,0.25,4.0xx10^(-6)),(3,0.25,0.50,8.0xx10^(-6)):} The overall of the reaction is

The following data is given at 27^(@)C for the reaction xA+yB rarr product . {:("Trial. ",[A]"mol / L ",[B]"mol/L ","Rate (M s^(-1))),(1,0.01,0.01,10^(-6)),(2,0.01,0.02,2xx10^(-6)),(3,0.04,0.02,32xx10^(-6)):} If reaction is elementary,then select the correct relation. (A) x=y+2 (B) y=x+2 (C)x=y (D) x=y+1

For the reaction A + B to products, the following initial rates were obtained at various given initial concentration {:("S.No.",,"[A]mol/L",,"[B] mol/L",,"Initial rate M/s"),(1.,," "0.1,," "0.1,," "0.05),(2.,," "0.2,," "0.1,," "0.10),(3.,," 0.1",," 0.2",," 0.05"):} Determine the half-life period.

DINESH PUBLICATION-NUCLEAR AND RADIO CHEMISTRY-Evaluate Yourself
  1. The enthaply change, DeltaH, in a simple one step reaction is gt 0, so...

    Text Solution

    |

  2. The half life of a first order reaction is 60 sec . The percentage of ...

    Text Solution

    |

  3. If the reaction , A + B to C+D , is thermodynamically feasible, the ti...

    Text Solution

    |

  4. For a hypothetical reaction, the following kinetic data suggested that...

    Text Solution

    |

  5. A reaction rate contant doubles between 300 and 310 k. By which of the...

    Text Solution

    |

  6. If t(0.5) of a first order reaction, PCl(5) to PCl(3) + Cl(2) is 10 mi...

    Text Solution

    |

  7. The d-orbital involved in sp^3d hybridisation is

    Text Solution

    |

  8. A molecules ML(5) contains 5 s bonding pairs of electrons and one non-...

    Text Solution

    |

  9. If heat of formation of HI in the given reactions (i) H(2)(g) + I(2)...

    Text Solution

    |

  10. The entropy change produced in universe when 3.6 kg of water of 47^(@)...

    Text Solution

    |

  11. A sample of radioactive element undergoes 90% decomposition in 336 min...

    Text Solution

    |

  12. The vant Hoff factor (i) for a dilute solution of potassium aluminium ...

    Text Solution

    |

  13. A 0.01 M solution of glucose in water freezes at -0.0186^(@)C A 0.01 M...

    Text Solution

    |

  14. 20 mL of HCl having a certain normality neutralises exactly 1.0 g CaCO...

    Text Solution

    |

  15. The potential of an electrode is represented as Pt. (0.25 atm)//H^(+) ...

    Text Solution

    |

  16. For the cell reaction , |Cu| Cu^(2+)(aq)|Ag^(+)|Ag is E^(@) Cu^(2)|Cu=...

    Text Solution

    |

  17. Which of the following is not possible ?

    Text Solution

    |

  18. For a reaction, SO(2) (g) + 1//2O(2)(g) to SO(3)(g) if K(p)=1.7 xx10...

    Text Solution

    |

  19. A radioactive isotope having t(1//2) =3 days was read after 12 days ....

    Text Solution

    |

  20. The number of alpha and beta -particle emitted in the transformation ...

    Text Solution

    |