Colligative Properties: Osmotic pressure, Vant Hoff factor.

Vant Hoff factor (i)-

Assertion: Osmotic pressure is a colligative property. Reason: Osmotic pressure of a solution at any temperature T depends on the molar concentration.

Colligative property is 1.Osmotic pressure 2. Vapour pressure 3.Cohesion force 4.Surface tension

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . van't Hoff coefficient 'g' for 100% dissociated NaCl solution is:

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . van,t Hoff factor (i) for dimerisation of benzoic acid in water, assuming 30% degree of association is:

Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i). What is observed molar mass of weak acid in soluton in above equation?