Home
Class 11
CHEMISTRY
The best method to prepare 3-methylbutan...

The best method to prepare 3-methylbutane-2-ol from 3-methylbut-1-ene is

A

addition of water in the presence of dil. `H_(2)SO_(4)`

B

addition of HBr in the presence of peroxide followed by reaction with dil. NaOH(aq)

C

hydroboration-oxidation reaction

D

oxymercuration-demercuration reaction

Text Solution

Verified by Experts

The correct Answer is:
C

In this conversion, anti-Markownikoff's addition of water is required and that too without any rearrangement. Therefore the best method in this case is hydroboration oxidation reaction.
`underset("3-Methylbut-1-ene")(CH_(3)-overset(CH_(3))overset(|)(CH)-CH=CH_(2)) underset((ii) H_(2)O_(2)//OH^(-))overset((i) (BH_(3))_(2))rarr underset("3-Methylbutane-1-ol")(CH_(3)-overset(CH_(3))overset(|)(CH)-CH_(2)-overset(H)overset(|)(CH_(2))`
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise RQ|225 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise Selected Straight Objective Type MCQs|55 Videos
  • APPENDICES

    DINESH PUBLICATION|Exercise Multiple choice|76 Videos

Similar Questions

Explore conceptually related problems

3-methylbut-3-en-1-ol

The best method to prepare cyclohexene from cyclohexanol is by using

DINESH PUBLICATION-ALCOHOLS AND PHENOLS-Ultimate Preparatory Package
  1. The best method to prepare 3-methylbutane-2-ol from 3-methylbut-1-ene ...

    Text Solution

    |

  2. Addition of water to 3-methylbut-1-ene in the presence of dil. H(2)SO...

    Text Solution

    |

  3. Best method to prepare trans-2methylcyclohexanol from 1-methyl-cyclohe...

    Text Solution

    |

  4. Cinnamic aldehyde can be converted into cinnamyl alcohol by

    Text Solution

    |

  5. Norbornene can be converted into exo-norborneol by

    Text Solution

    |

  6. Methlamine on treatment with nitrous acid gives

    Text Solution

    |

  7. When few drops of glycerol is put on powdered KMnO(4)

    Text Solution

    |

  8. The butyl alcohol which gives iodoform test is

    Text Solution

    |

  9. The final product Y in the following reaction is CH(3)CH(2)CH=CH(2) ...

    Text Solution

    |

  10. The product obtained in the following reaction is

    Text Solution

    |

  11. The correct order of reactivity of following alcohols with HBr is (...

    Text Solution

    |

  12. The major product formed in the following reaction is

    Text Solution

    |

  13. The correct order of ease of dehydration of following is

    Text Solution

    |

  14. Which of the following reagent can be used to convert trans-2-butene t...

    Text Solution

    |

  15. An alcohol on treatment with alkaline KMnO(4) gives brown ppt. The alc...

    Text Solution

    |

  16. The intermediate formed in the acid catalysed dehydration of n-propyl ...

    Text Solution

    |

  17. The reaction of neopentyl alcohol with concentrated HCl gives

    Text Solution

    |

  18. Choose the correct statement for the reaction

    Text Solution

    |

  19. An unknown compound on oxidative cleavage (HIO(4)) forms one mole each...

    Text Solution

    |

  20. The number of optically active isomers possible for the compound CH(...

    Text Solution

    |

  21. In which of the following compounds, the -OH group is least reactive

    Text Solution

    |