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The correct order of increasing basicity...

The correct order of increasing basicity of the following is
`H_(2)O, OH^(-), CH_(3)OH, CH_(3)O^(-)`

A

`CH_(3)OH lt H_(2)O lt OH^(-) lt CH_(3)O^(-)`

B

`H_(2)O lt CH_(3)OH lt CH_(3)O^(-) lt OH^(-)`

C

`H_(2)O lt CH_(3)OH lt OH^(-) lt CH_(3)O^(-)`

D

`CH_(3)OH lt H_(2)O lt CH_(3)O^(-) lt OH^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing basicity among the given compounds: H₂O, OH⁻, CH₃OH, and CH₃O⁻, we need to analyze the basicity of each compound based on their ability to donate a lone pair of electrons and accept protons (H⁺). ### Step-by-Step Solution: 1. **Understanding Basicity**: Basicity refers to the ability of a species to accept protons (H⁺) or donate electron pairs. A stronger base is more likely to donate its electrons or accept protons. 2. **Analyzing CH₃O⁻ (Methoxide Ion)**: - CH₃O⁻ has a negative charge on oxygen, which increases its electron density, making it very reactive and a strong base. - The presence of the methyl group (CH₃) enhances the electron density on oxygen due to the +I (inductive) effect, making it more likely to donate its electrons. 3. **Analyzing OH⁻ (Hydroxide Ion)**: - OH⁻ also has a negative charge on oxygen, but it is less basic than CH₃O⁻. - The hydroxide ion is a strong base, but the electron-donating effect of the hydrogen atom is weaker compared to the methyl group in CH₃O⁻. 4. **Analyzing CH₃OH (Methanol)**: - CH₃OH has a hydroxyl group (-OH) but lacks a negative charge. - While it can donate a lone pair, it is less basic than both OH⁻ and CH₃O⁻ because it does not have a negative charge to facilitate proton acceptance. 5. **Analyzing H₂O (Water)**: - H₂O is the least basic among the four. - It can donate a lone pair but does not have a negative charge, making it less likely to accept protons compared to the other species. 6. **Final Order of Basicity**: - Based on the analysis, we can arrange the compounds in order of increasing basicity: - H₂O < CH₃OH < OH⁻ < CH₃O⁻ ### Conclusion: The correct order of increasing basicity is: **H₂O < CH₃OH < OH⁻ < CH₃O⁻**

To determine the correct order of increasing basicity among the given compounds: H₂O, OH⁻, CH₃OH, and CH₃O⁻, we need to analyze the basicity of each compound based on their ability to donate a lone pair of electrons and accept protons (H⁺). ### Step-by-Step Solution: 1. **Understanding Basicity**: Basicity refers to the ability of a species to accept protons (H⁺) or donate electron pairs. A stronger base is more likely to donate its electrons or accept protons. 2. **Analyzing CH₃O⁻ (Methoxide Ion)**: - CH₃O⁻ has a negative charge on oxygen, which increases its electron density, making it very reactive and a strong base. ...
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