Home
Class 11
CHEMISTRY
When the following aldohexose exists in ...

When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its pyranose form, is
`{:(CHO),(|),(CH_(2)),(|),(CHOH),(|),(CHOH),(|),(CHOH),(|),(CH_(2)OH):}`

A

4

B

8

C

16

D

none of these

Text Solution

Verified by Experts

The correct Answer is:
B

The D-form of given sugar is
`{:(" "CHO),(" |"),(" "CH_(2)),(" |"),(" "CHOH),(" |"),(" "CHOH),(" |"),(H-C-OH),(" |"),(" "CH_(2)OH):}" " overset("Cyclisation")to`

Configuration at the the three chiral carbons (C-1 ,C-3 and C-4 ) can be change maintaining D-configuration).
`:.` The total number of stereoisomers =`2^(2)=8`
Promotional Banner

Similar Questions

Explore conceptually related problems

When the following aldohexose exists in its D-configuration, the total number of stereisomers in its pyranose form is : .

When the following aldohexose exists in Pyranose from, the total number of stereoisomers in its pyranose form is

When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its pyranose form is. OHC-CH_(2)-underset(OH)underset("| ")"CH"-underset(OH)underset("| ")"CH"-underset(OH)underset("| ")"CH"-CH_(2)-OH

{:(" "CH_(3)),(" "|),(CH_(2)=CHCH_(2)-CHOH):}

CH_(2)OH-CHOH-CH_(2)OH