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Which statement is not correct about NO(...

Which statement is not correct about `NO_(2)` ?

A

It is paramagnetic

B

It forms dimer and paramanetism is lost

C

It has one coordinate bond

D

It has nitrogen oxygen triple bond

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is not correct about \( NO_2 \), we will analyze the properties and structure of the molecule step by step. ### Step 1: Understand the Valence Electrons - Nitrogen (N) has 5 valence electrons. - Each Oxygen (O) has 6 valence electrons. - In \( NO_2 \), there are one nitrogen and two oxygen atoms, giving a total of \( 5 + 2 \times 6 = 17 \) valence electrons. **Hint:** Count the total number of valence electrons from all atoms involved in the molecule. ### Step 2: Draw the Lewis Structure - Nitrogen forms a double bond with one oxygen atom and a single bond with the other oxygen atom. - The single bond oxygen has a lone pair, which can be donated to nitrogen, forming a coordinate bond. - This results in nitrogen having a formal charge of +1 and one of the oxygen atoms having a formal charge of -1. **Hint:** Use the octet rule to guide how bonds are formed and how lone pairs are distributed. ### Step 3: Determine the Magnetic Properties - To check if \( NO_2 \) is paramagnetic, we need to look for unpaired electrons. - In the Lewis structure, nitrogen has one unpaired electron after forming the bonds, which makes \( NO_2 \) paramagnetic. **Hint:** Remember that paramagnetic species have unpaired electrons, while diamagnetic species do not. ### Step 4: Analyze the Bonding - The bonds in \( NO_2 \) consist of one double bond and one coordinate bond. - The statement claiming that there is a nitrogen-oxygen triple bond is incorrect, as \( NO_2 \) only has one double bond and one coordinate bond. **Hint:** Verify each bond type and count to ensure accuracy in the bonding description. ### Step 5: Identify the Incorrect Statement - Based on the analysis: - \( NO_2 \) is paramagnetic (correct). - \( NO_2 \) has one coordinate bond (correct). - The incorrect statement is that \( NO_2 \) has a nitrogen-oxygen triple bond. **Hint:** Compare the statements given in the question with your findings to identify which one does not align with the established facts. ### Conclusion The statement that is not correct about \( NO_2 \) is that it has a nitrogen-oxygen triple bond. The correct bonding in \( NO_2 \) consists of one double bond and one coordinate bond.

To determine which statement is not correct about \( NO_2 \), we will analyze the properties and structure of the molecule step by step. ### Step 1: Understand the Valence Electrons - Nitrogen (N) has 5 valence electrons. - Each Oxygen (O) has 6 valence electrons. - In \( NO_2 \), there are one nitrogen and two oxygen atoms, giving a total of \( 5 + 2 \times 6 = 17 \) valence electrons. **Hint:** Count the total number of valence electrons from all atoms involved in the molecule. ...
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