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The group of molecules having identical ...

The group of molecules having identical shape is:

A

`SF_(4), XeF_(4), C Cl_(4)`

B

`ClF_(3), XeOF_(2), XeF_(3)^(+)`

C

`BF_(3), PCl_(3), XeO_(3)`

D

`PCl_(5), IF_(5), XeO_(2)F_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question about identifying the group of molecules having identical shapes, we will analyze the given options step by step. ### Step 1: Analyze Option A - **Molecules**: SF4 and XeF4 - **SF4 (Sulfur Tetrafluoride)**: - Valence electrons: Sulfur has 6 valence electrons. - Structure: 4 fluorine atoms bonded to sulfur, with 1 lone pair on sulfur. - Shape: Seesaw (due to 4 bond pairs and 1 lone pair). - Hybridization: sp³d. - **XeF4 (Xenon Tetrafluoride)**: - Valence electrons: Xenon has 8 valence electrons. - Structure: 4 fluorine atoms in the plane and 2 lone pairs on xenon. - Shape: Square planar (due to 4 bond pairs and 2 lone pairs). - Hybridization: sp³d². **Conclusion for Option A**: The shapes are different (seesaw vs. square planar), so this option is not correct. ### Step 2: Analyze Option B - **Molecules**: ClF3, XeOF2, and XeF3+ - **ClF3 (Chlorine Trifluoride)**: - Valence electrons: Chlorine has 7 valence electrons. - Structure: 3 fluorine atoms bonded to chlorine, with 2 lone pairs on chlorine. - Shape: T-shaped (due to 3 bond pairs and 2 lone pairs). - Hybridization: sp³d. - **XeOF2 (Xenon Oxyfluoride)**: - Valence electrons: Xenon has 8 valence electrons, and oxygen contributes 2. - Structure: 2 fluorine atoms bonded to xenon, with 2 lone pairs on xenon. - Shape: T-shaped (due to 3 bond pairs and 2 lone pairs). - Hybridization: sp³d. - **XeF3+ (Xenon Trifluoride cation)**: - Valence electrons: Xenon has 8 electrons, minus 1 for the positive charge gives 7. - Structure: 3 fluorine atoms bonded to xenon, with 2 lone pairs on xenon. - Shape: T-shaped (due to 3 bond pairs and 2 lone pairs). - Hybridization: sp³d. **Conclusion for Option B**: All three molecules (ClF3, XeOF2, and XeF3+) have the same shape (T-shaped), so this option is correct. ### Step 3: Analyze Option C - **Molecules**: BF3 and PCl3 - **BF3 (Boron Trifluoride)**: - Valence electrons: Boron has 3 valence electrons. - Structure: 3 fluorine atoms bonded to boron, no lone pairs. - Shape: Trigonal planar (due to 3 bond pairs). - Hybridization: sp². - **PCl3 (Phosphorus Trichloride)**: - Valence electrons: Phosphorus has 5 valence electrons. - Structure: 3 chlorine atoms bonded to phosphorus, with 1 lone pair on phosphorus. - Shape: Trigonal pyramidal (due to 3 bond pairs and 1 lone pair). - Hybridization: sp³. **Conclusion for Option C**: The shapes are different (trigonal planar vs. trigonal pyramidal), so this option is not correct. ### Step 4: Analyze Option D - **Molecules**: PCl5 and IF5 - **PCl5 (Phosphorus Pentachloride)**: - Valence electrons: Phosphorus has 5 valence electrons. - Structure: 5 chlorine atoms bonded to phosphorus, no lone pairs. - Shape: Trigonal bipyramidal (due to 5 bond pairs). - Hybridization: sp³d. - **IF5 (Iodine Pentafluoride)**: - Valence electrons: Iodine has 7 valence electrons. - Structure: 5 fluorine atoms bonded to iodine, with 1 lone pair on iodine. - Shape: Square pyramidal (due to 5 bond pairs and 1 lone pair). - Hybridization: sp³d². **Conclusion for Option D**: The shapes are different (trigonal bipyramidal vs. square pyramidal), so this option is not correct. ### Final Answer: The correct group of molecules having identical shape is **Option B: ClF3, XeOF2, and XeF3+**.

To solve the question about identifying the group of molecules having identical shapes, we will analyze the given options step by step. ### Step 1: Analyze Option A - **Molecules**: SF4 and XeF4 - **SF4 (Sulfur Tetrafluoride)**: - Valence electrons: Sulfur has 6 valence electrons. - Structure: 4 fluorine atoms bonded to sulfur, with 1 lone pair on sulfur. - Shape: Seesaw (due to 4 bond pairs and 1 lone pair). ...
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